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Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex.
Org Biomol Chem. 2014 Mar 28; 12(12):1935-41.OB

Abstract

The asymmetric α-amination of alkenyl trifluoroacetates with dialkyl azodicarboxylates catalyzed by the DTBM-SEGPHOS·AgOTf complex takes place in the presence of 2,2,2-trifluoroethanol with almost quantitative yield and high ees of up to 97%.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Yanagisawa A
Department of Chemistry, Graduate School of Science, Chiba University, Inage, Chiba 263-8522, Japan. ayanagi@faculty.chiba-u.jp.
Miyake R
No affiliation info available
Yoshida K
No affiliation info available

MeSH

AlkenesAminationCatalysisKetonesMolecular StructureOrganometallic CompoundsPhosphinesSilverTrifluoroacetic Acid

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24526286

Citation

Yanagisawa, Akira, et al. "Asymmetric Α-amination Reaction of Alkenyl Trifluoroacetates Catalyzed By a Chiral Phosphine-silver Complex." Organic & Biomolecular Chemistry, vol. 12, no. 12, 2014, pp. 1935-41.
Yanagisawa A, Miyake R, Yoshida K. Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex. Org Biomol Chem. 2014;12(12):1935-41.
Yanagisawa, A., Miyake, R., & Yoshida, K. (2014). Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex. Organic & Biomolecular Chemistry, 12(12), 1935-41. https://doi.org/10.1039/c3ob42111b
Yanagisawa A, Miyake R, Yoshida K. Asymmetric Α-amination Reaction of Alkenyl Trifluoroacetates Catalyzed By a Chiral Phosphine-silver Complex. Org Biomol Chem. 2014 Mar 28;12(12):1935-41. PubMed PMID: 24526286.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex. AU - Yanagisawa,Akira, AU - Miyake,Ryoji, AU - Yoshida,Kazuhiro, Y1 - 2014/02/14/ PY - 2014/2/15/entrez PY - 2014/2/15/pubmed PY - 2014/10/14/medline SP - 1935 EP - 41 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 12 IS - 12 N2 - The asymmetric α-amination of alkenyl trifluoroacetates with dialkyl azodicarboxylates catalyzed by the DTBM-SEGPHOS·AgOTf complex takes place in the presence of 2,2,2-trifluoroethanol with almost quantitative yield and high ees of up to 97%. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/24526286/Asymmetric_α_amination_reaction_of_alkenyl_trifluoroacetates_catalyzed_by_a_chiral_phosphine_silver_complex_ DB - PRIME DP - Unbound Medicine ER -