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A new electrochemical sensor of nitro aromatic compound based on three-dimensional porous Pt-Pd nanoparticles supported by graphene-multiwalled carbon nanotube composite.
Biosens Bioelectron. 2014 Aug 15; 58:85-91.BB

Abstract

In this study, an electrochemical sensor of nitro aromatic compound based on three-dimensional porous Pt-Pd nanoparticles (Pt-Pd NPs) supported by reduced graphene oxide (rGO) nanosheets-multiwalled carbon nanotube (CNTs) nanocomposite (marked as Pt-Pd NPs/CNTs-rGO) was investigated for the first time. This hybrid nanocomposite has been prepared via a facile and versatile hydrothermal synthetic strategy while its structure and property are evaluated by X-ray diffraction (XRD), transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS). The result shows that 3D porous Pt-Pd NPs/CNTs-rGO nanocomposite has a large specific surface area of 326.6m(2)g(-1) and exhibited ultrahigh rate capability and good cycling properties at high rates. Electrochemical studies have been performed for the nitro aromatic compounds detection by using different pulse voltammetry (DPV) techniques. The proposed nanocomposite exhibited much enhanced elctrocatalytic activity and high sensitivity toward the detection of nitro aromatic compounds which compared with Pt-Pd NPs dispersed on functionalized rGO, Pt-Pd NPs dispersed on functionalized CNTs, rGO-CNTs and bare glass carbon electrode (GCE). On the basis of the above synergetic electrochemical sensing and synthesis procedure, the hybrid material can be recommended as a robust material for sensor-related applications. Moreover, the proposed sensor exhibits high reproducibility, long-time storage stability and satisfactory anti-interference ability.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.

College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, China.

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China. Electronic address: luxq@nwnu.edu.cn.

MeSH

ConductometryEquipment DesignEquipment Failure AnalysisGraphiteHydrocarbons, AromaticMetal NanoparticlesMicroelectrodesMolecular ConformationNanocompositesNanoporesNanotubes, CarbonNitro CompoundsPalladiumPlatinumPorosity

Pub Type(s)

Journal Article

Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24632133

Citation

Yuan, Cai-Xia, et al. "A New Electrochemical Sensor of Nitro Aromatic Compound Based On Three-dimensional Porous Pt-Pd Nanoparticles Supported By Graphene-multiwalled Carbon Nanotube Composite." Biosensors & Bioelectronics, vol. 58, 2014, pp. 85-91.

Yuan CX, Fan YR, Tao-Zhang , et al. A new electrochemical sensor of nitro aromatic compound based on three-dimensional porous Pt-Pd nanoparticles supported by graphene-multiwalled carbon nanotube composite. Biosens Bioelectron. 2014;58:85-91.

Yuan, C. X., Fan, Y. R., Tao-Zhang, ., Guo, H. X., Zhang, J. X., Wang, Y. L., Shan, D. L., & Lu, X. Q. (2014). A new electrochemical sensor of nitro aromatic compound based on three-dimensional porous Pt-Pd nanoparticles supported by graphene-multiwalled carbon nanotube composite. Biosensors & Bioelectronics, 58, 85-91. https://doi.org/10.1016/j.bios.2014.01.041

Yuan CX, et al. A New Electrochemical Sensor of Nitro Aromatic Compound Based On Three-dimensional Porous Pt-Pd Nanoparticles Supported By Graphene-multiwalled Carbon Nanotube Composite. Biosens Bioelectron. 2014 Aug 15;58:85-91. PubMed PMID: 24632133.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - A new electrochemical sensor of nitro aromatic compound based on three-dimensional porous Pt-Pd nanoparticles supported by graphene-multiwalled carbon nanotube composite. AU - Yuan,Cai-Xia, AU - Fan,Yan-Ru, AU - Tao-Zhang,, AU - Guo,Hui-Xia, AU - Zhang,Jing-Xuan, AU - Wang,Yong-Lan, AU - Shan,Duo-Liang, AU - Lu,Xiao-Quan, Y1 - 2014/02/25/ PY - 2013/11/22/received PY - 2014/01/20/revised PY - 2014/01/23/accepted PY - 2014/3/18/entrez PY - 2014/3/19/pubmed PY - 2015/5/15/medline KW - Carbon nanotube KW - Graphene KW - Nitro aromatic compounds KW - Pt–Pd nanoparticles SP - 85 EP - 91 JF - Biosensors & bioelectronics JO - Biosens Bioelectron VL - 58 N2 - In this study, an electrochemical sensor of nitro aromatic compound based on three-dimensional porous Pt-Pd nanoparticles (Pt-Pd NPs) supported by reduced graphene oxide (rGO) nanosheets-multiwalled carbon nanotube (CNTs) nanocomposite (marked as Pt-Pd NPs/CNTs-rGO) was investigated for the first time. This hybrid nanocomposite has been prepared via a facile and versatile hydrothermal synthetic strategy while its structure and property are evaluated by X-ray diffraction (XRD), transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS). The result shows that 3D porous Pt-Pd NPs/CNTs-rGO nanocomposite has a large specific surface area of 326.6m(2)g(-1) and exhibited ultrahigh rate capability and good cycling properties at high rates. Electrochemical studies have been performed for the nitro aromatic compounds detection by using different pulse voltammetry (DPV) techniques. The proposed nanocomposite exhibited much enhanced elctrocatalytic activity and high sensitivity toward the detection of nitro aromatic compounds which compared with Pt-Pd NPs dispersed on functionalized rGO, Pt-Pd NPs dispersed on functionalized CNTs, rGO-CNTs and bare glass carbon electrode (GCE). On the basis of the above synergetic electrochemical sensing and synthesis procedure, the hybrid material can be recommended as a robust material for sensor-related applications. Moreover, the proposed sensor exhibits high reproducibility, long-time storage stability and satisfactory anti-interference ability. SN - 1873-4235 UR - https://www.unboundmedicine.com/medline/citation/24632133/A_new_electrochemical_sensor_of_nitro_aromatic_compound_based_on_three_dimensional_porous_Pt_Pd_nanoparticles_supported_by_graphene_multiwalled_carbon_nanotube_composite_ DB - PRIME DP - Unbound Medicine ER -