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Rhodium-catalyzed direct ortho C-N bond formation of aromatic azo compounds with azides.
J Org Chem. 2014 Apr 04; 79(7):3279-88.JO

Abstract

An efficient rhodium-catalyzed regioselective C-N bond formation of azo compounds in good to excellent yields through C-H bond functionalization using azides as the nitrogen source was developed. Alkyl, aryl, and sulfonyl azides could be efficiently assembled in this reaction with excellent functional group tolerance.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Wang H
Department of Chemistry, Innovative Drug Research Center, Shanghai University , Shanghai 200444, China.
Yu Y
No affiliation info available
Hong X
No affiliation info available
Tan Q
No affiliation info available
Xu B
No affiliation info available

MeSH

AzidesAzo CompoundsCatalysisHydrogen BondingMolecular StructureRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24635190

Citation

Wang, Hao, et al. "Rhodium-catalyzed Direct Ortho C-N Bond Formation of Aromatic Azo Compounds With Azides." The Journal of Organic Chemistry, vol. 79, no. 7, 2014, pp. 3279-88.
Wang H, Yu Y, Hong X, et al. Rhodium-catalyzed direct ortho C-N bond formation of aromatic azo compounds with azides. J Org Chem. 2014;79(7):3279-88.
Wang, H., Yu, Y., Hong, X., Tan, Q., & Xu, B. (2014). Rhodium-catalyzed direct ortho C-N bond formation of aromatic azo compounds with azides. The Journal of Organic Chemistry, 79(7), 3279-88. https://doi.org/10.1021/jo500412w
Wang H, et al. Rhodium-catalyzed Direct Ortho C-N Bond Formation of Aromatic Azo Compounds With Azides. J Org Chem. 2014 Apr 4;79(7):3279-88. PubMed PMID: 24635190.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed direct ortho C-N bond formation of aromatic azo compounds with azides. AU - Wang,Hao, AU - Yu,Yang, AU - Hong,Xiaohu, AU - Tan,Qitao, AU - Xu,Bin, Y1 - 2014/03/24/ PY - 2014/3/19/entrez PY - 2014/3/19/pubmed PY - 2015/1/21/medline SP - 3279 EP - 88 JF - The Journal of organic chemistry JO - J Org Chem VL - 79 IS - 7 N2 - An efficient rhodium-catalyzed regioselective C-N bond formation of azo compounds in good to excellent yields through C-H bond functionalization using azides as the nitrogen source was developed. Alkyl, aryl, and sulfonyl azides could be efficiently assembled in this reaction with excellent functional group tolerance. SN - 1520-6904 UR - https://www.unboundmedicine.com/medline/citation/24635190/Rhodium_catalyzed_direct_ortho_C_N_bond_formation_of_aromatic_azo_compounds_with_azides_ DB - PRIME DP - Unbound Medicine ER -