Tags

Type your tag names separated by a space and hit enter

Highly versatile Pd-thioether-phosphite catalytic systems for asymmetric allylic alkylation, amination, and etherification reactions.
Org Lett. 2014 Apr 04; 16(7):1892-5.OL

Abstract

A Pd-furanoside thioether-phosphite catalytic system that can create new C-C, C-N, and C-O bonds in several substrate types using a wide range of nucleophiles in high yields and enantioselectivities has been identified. Of particular note are the excellent enantioselectivities obtained in the etherification of linear and cyclic substrates. The potential application of the new Pd-thioether-phosphite catalytic systems was also demonstrated by the synthesis of the chiral carbo- and heterocycles.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Coll M
Departament de Química Física i Inorgànica, Universitat Rovira i Virgili , C/Marcel·lí Domingo, s/n, 43007 Tarragona, Spain.
Pàmies O
No affiliation info available
Diéguez M
No affiliation info available

MeSH

AlkylationAllyl CompoundsAminationCatalysisCombinatorial Chemistry TechniquesMolecular StructureOrganophosphorus CompoundsPalladiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24661010

Citation

Coll, Mercè, et al. "Highly Versatile Pd-thioether-phosphite Catalytic Systems for Asymmetric Allylic Alkylation, Amination, and Etherification Reactions." Organic Letters, vol. 16, no. 7, 2014, pp. 1892-5.
Coll M, Pàmies O, Diéguez M. Highly versatile Pd-thioether-phosphite catalytic systems for asymmetric allylic alkylation, amination, and etherification reactions. Org Lett. 2014;16(7):1892-5.
Coll, M., Pàmies, O., & Diéguez, M. (2014). Highly versatile Pd-thioether-phosphite catalytic systems for asymmetric allylic alkylation, amination, and etherification reactions. Organic Letters, 16(7), 1892-5. https://doi.org/10.1021/ol500758y
Coll M, Pàmies O, Diéguez M. Highly Versatile Pd-thioether-phosphite Catalytic Systems for Asymmetric Allylic Alkylation, Amination, and Etherification Reactions. Org Lett. 2014 Apr 4;16(7):1892-5. PubMed PMID: 24661010.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly versatile Pd-thioether-phosphite catalytic systems for asymmetric allylic alkylation, amination, and etherification reactions. AU - Coll,Mercè, AU - Pàmies,Oscar, AU - Diéguez,Montserrat, Y1 - 2014/03/24/ PY - 2014/3/26/entrez PY - 2014/3/26/pubmed PY - 2014/6/21/medline SP - 1892 EP - 5 JF - Organic letters JO - Org Lett VL - 16 IS - 7 N2 - A Pd-furanoside thioether-phosphite catalytic system that can create new C-C, C-N, and C-O bonds in several substrate types using a wide range of nucleophiles in high yields and enantioselectivities has been identified. Of particular note are the excellent enantioselectivities obtained in the etherification of linear and cyclic substrates. The potential application of the new Pd-thioether-phosphite catalytic systems was also demonstrated by the synthesis of the chiral carbo- and heterocycles. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/24661010/Highly_versatile_Pd_thioether_phosphite_catalytic_systems_for_asymmetric_allylic_alkylation_amination_and_etherification_reactions_ DB - PRIME DP - Unbound Medicine ER -