TY - JOUR T1 - Amide-linked N-methacryloyl sucrose containing polymers. AU - Petrova,Krasimira T, AU - Potewar,Taterao M, AU - Ascenso,Osvaldo S, AU - Barros,M Teresa, Y1 - 2014/03/28/ PY - 2013/05/27/received PY - 2014/03/04/revised PY - 2014/03/19/accepted PY - 2014/6/8/entrez PY - 2014/6/8/pubmed PY - 2015/10/20/medline KW - Amide-linkage KW - Free radical copolymerization KW - N-methacryloyl monomers KW - Poly(vinylsacharides) KW - Sucrose-containing monomers SP - 38 EP - 46 JF - Carbohydrate polymers JO - Carbohydr Polym VL - 110 N2 - 1',2,3,3',4,4',6-Hepta-O-benzyl-6'-N-methacryloyl-6'-deoxysucrose 1, 6'-deoxy-6'-N-methacryloyloxyethylureido sucrose 2 and 6,6'-dideoxy-6,6'-N-dimethacryloyloxyethylureido sucrose 3 have been homo-polymerized and copolymerized with styrene by a free radical process, yielding polymer materials with pendant sucrose moieties, attached to the polymer backbone via amide linkages. The results demonstrated that varying the structural features of the monomers, greatly affected the thermal and rheological properties of the polymers. The polymer materials obtained have been characterized by NMR, MALDI-TOF, DSC, AFM and EWC (equilibrium water content). The efficient synthesis of the three novel, regioisomerically pure, N-methacryloylamide sucrose-containing monomers (1, 2 and 3) have been described. SN - 1879-1344 UR - https://www.unboundmedicine.com/medline/citation/24906726/Amide_linked_N_methacryloyl_sucrose_containing_polymers_ DB - PRIME DP - Unbound Medicine ER -