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Pd(0)-catalyzed alkenylation and allylic dearomatization reactions between nucleophile-bearing indoles and propargyl carbonate.
Org Lett. 2014 Aug 01; 16(15):3919-21.OL

Abstract

Spiroindolenine derivatives were synthesized by intermolecular Pd-catalyzed dearomatization of indoles. The reaction between nucleophile bearing indoles and propargyl carbonate proceeds in a cascade fashion providing spiroindolenines or spiroindolines in good to excellent yields.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Gao RD
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Lu, Shanghai 200032, China.
Liu C
No affiliation info available
Dai LX
No affiliation info available
Zhang W
No affiliation info available
You SL
No affiliation info available

MeSH

AlkynesCarbonatesCatalysisIndolesMolecular StructurePalladiumSpiro CompoundsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24992703

Citation

Gao, Run-Duo, et al. "Pd(0)-catalyzed Alkenylation and Allylic Dearomatization Reactions Between Nucleophile-bearing Indoles and Propargyl Carbonate." Organic Letters, vol. 16, no. 15, 2014, pp. 3919-21.
Gao RD, Liu C, Dai LX, et al. Pd(0)-catalyzed alkenylation and allylic dearomatization reactions between nucleophile-bearing indoles and propargyl carbonate. Org Lett. 2014;16(15):3919-21.
Gao, R. D., Liu, C., Dai, L. X., Zhang, W., & You, S. L. (2014). Pd(0)-catalyzed alkenylation and allylic dearomatization reactions between nucleophile-bearing indoles and propargyl carbonate. Organic Letters, 16(15), 3919-21. https://doi.org/10.1021/ol501704q
Gao RD, et al. Pd(0)-catalyzed Alkenylation and Allylic Dearomatization Reactions Between Nucleophile-bearing Indoles and Propargyl Carbonate. Org Lett. 2014 Aug 1;16(15):3919-21. PubMed PMID: 24992703.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Pd(0)-catalyzed alkenylation and allylic dearomatization reactions between nucleophile-bearing indoles and propargyl carbonate. AU - Gao,Run-Duo, AU - Liu,Chuan, AU - Dai,Li-Xin, AU - Zhang,Wei, AU - You,Shu-Li, Y1 - 2014/07/03/ PY - 2014/7/4/entrez PY - 2014/7/6/pubmed PY - 2014/10/11/medline SP - 3919 EP - 21 JF - Organic letters JO - Org Lett VL - 16 IS - 15 N2 - Spiroindolenine derivatives were synthesized by intermolecular Pd-catalyzed dearomatization of indoles. The reaction between nucleophile bearing indoles and propargyl carbonate proceeds in a cascade fashion providing spiroindolenines or spiroindolines in good to excellent yields. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/24992703/Pd_0__catalyzed_alkenylation_and_allylic_dearomatization_reactions_between_nucleophile_bearing_indoles_and_propargyl_carbonate_ DB - PRIME DP - Unbound Medicine ER -