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Synthesis of 3-pyrrolin-2-ones by rhodium-catalyzed transannulation of 1-sulfonyl-1,2,3-triazole with ketene silyl acetal.
Org Lett. 2014 Jul 18; 16(14):3704-7.OL

Abstract

α-Imino rhodium carbenoids generated from 1-sulfonyl 1,2,3-triazole were applied to the 3 + 2 cycloaddition with ketene silyl acetal, offering a novel and straightforward synthesis of biologically interesting compound 3-pyrrolin-2-one with broad substrate scope.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Ran RQ
Department of Chemistry, Zhejiang Sci-Tech University , Xiasha West Higher Education District, Hangzhou 310018, China.
He J
No affiliation info available
Xiu SD
No affiliation info available
Wang KB
No affiliation info available
Li CY
No affiliation info available

MeSH

AcetalsCatalysisEthylenesKetonesPyrrolesRhodiumSilanesSulfonesTriazoles

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25004242

Citation

Ran, Rui-Qiao, et al. "Synthesis of 3-pyrrolin-2-ones By Rhodium-catalyzed Transannulation of 1-sulfonyl-1,2,3-triazole With Ketene Silyl Acetal." Organic Letters, vol. 16, no. 14, 2014, pp. 3704-7.
Ran RQ, He J, Xiu SD, et al. Synthesis of 3-pyrrolin-2-ones by rhodium-catalyzed transannulation of 1-sulfonyl-1,2,3-triazole with ketene silyl acetal. Org Lett. 2014;16(14):3704-7.
Ran, R. Q., He, J., Xiu, S. D., Wang, K. B., & Li, C. Y. (2014). Synthesis of 3-pyrrolin-2-ones by rhodium-catalyzed transannulation of 1-sulfonyl-1,2,3-triazole with ketene silyl acetal. Organic Letters, 16(14), 3704-7. https://doi.org/10.1021/ol501514b
Ran RQ, et al. Synthesis of 3-pyrrolin-2-ones By Rhodium-catalyzed Transannulation of 1-sulfonyl-1,2,3-triazole With Ketene Silyl Acetal. Org Lett. 2014 Jul 18;16(14):3704-7. PubMed PMID: 25004242.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Synthesis of 3-pyrrolin-2-ones by rhodium-catalyzed transannulation of 1-sulfonyl-1,2,3-triazole with ketene silyl acetal. AU - Ran,Rui-Qiao, AU - He,Jun, AU - Xiu,Shi-Dong, AU - Wang,Kai-Bing, AU - Li,Chuan-Ying, Y1 - 2014/07/08/ PY - 2014/7/9/entrez PY - 2014/7/9/pubmed PY - 2015/5/12/medline SP - 3704 EP - 7 JF - Organic letters JO - Org Lett VL - 16 IS - 14 N2 - α-Imino rhodium carbenoids generated from 1-sulfonyl 1,2,3-triazole were applied to the 3 + 2 cycloaddition with ketene silyl acetal, offering a novel and straightforward synthesis of biologically interesting compound 3-pyrrolin-2-one with broad substrate scope. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/25004242/Synthesis_of_3_pyrrolin_2_ones_by_rhodium_catalyzed_transannulation_of_1_sulfonyl_123_triazole_with_ketene_silyl_acetal_ DB - PRIME DP - Unbound Medicine ER -