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Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds.
J Org Chem. 2014 Aug 15; 79(16):7711-7.JO

Abstract

A palladium-catalyzed oxidative cross-coupling of vinyl boronic acids and cyclic α-diazocarbonyl compounds has been reported. The reaction constitutes an efficient method for the synthesis of 1,3-diene compounds bearing a ring structure. Mechanistically, the reaction involves migratory insertion of palladium carbene as the key step.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Xia Y
College of Chemical Engineering, Qingdao University of Science & Technology , Qingdao 266042, China.
Xia Y
No affiliation info available
Liu Z
No affiliation info available
Zhang Y
No affiliation info available
Wang J
No affiliation info available

MeSH

AlkenesAzo CompoundsBoronic AcidsMethaneMolecular StructureOxidation-ReductionPalladiumVinyl Compounds

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25019414

Citation

Xia, Yamu, et al. "Palladium-catalyzed Cross-coupling Reaction of Diazo Compounds and Vinyl Boronic Acids: an Approach to 1,3-diene Compounds." The Journal of Organic Chemistry, vol. 79, no. 16, 2014, pp. 7711-7.
Xia Y, Xia Y, Liu Z, et al. Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds. J Org Chem. 2014;79(16):7711-7.
Xia, Y., Xia, Y., Liu, Z., Zhang, Y., & Wang, J. (2014). Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds. The Journal of Organic Chemistry, 79(16), 7711-7. https://doi.org/10.1021/jo5012703
Xia Y, et al. Palladium-catalyzed Cross-coupling Reaction of Diazo Compounds and Vinyl Boronic Acids: an Approach to 1,3-diene Compounds. J Org Chem. 2014 Aug 15;79(16):7711-7. PubMed PMID: 25019414.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds. AU - Xia,Yamu, AU - Xia,Ying, AU - Liu,Zhen, AU - Zhang,Yan, AU - Wang,Jianbo, Y1 - 2014/07/24/ PY - 2014/7/15/entrez PY - 2014/7/16/pubmed PY - 2015/2/24/medline SP - 7711 EP - 7 JF - The Journal of organic chemistry JO - J Org Chem VL - 79 IS - 16 N2 - A palladium-catalyzed oxidative cross-coupling of vinyl boronic acids and cyclic α-diazocarbonyl compounds has been reported. The reaction constitutes an efficient method for the synthesis of 1,3-diene compounds bearing a ring structure. Mechanistically, the reaction involves migratory insertion of palladium carbene as the key step. SN - 1520-6904 UR - https://www.unboundmedicine.com/medline/citation/25019414/Palladium_catalyzed_cross_coupling_reaction_of_diazo_compounds_and_vinyl_boronic_acids:_an_approach_to_13_diene_compounds_ DB - PRIME DP - Unbound Medicine ER -