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Pd-catalyzed [3+2] cycloaddition of ketoimines with alkynes via directed sp³ C-H bond activation.
Chem Commun (Camb). 2014 Sep 21; 50(73):10699-702.CC

Abstract

The Pd(II)-catalyzed oxidative [3+2] cycloaddition of N-(2-pyridyl) ketoimines with internal alkynes has been developed. The transformation is tolerant of extensive substitution on halogen, alkene, alkyne, hydroxyl, aryl and acyl groups, and allows facile assembly of multisubstituted pyrroles.

Authors+Show Affiliations

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China. zengwei@scut.edu.cn.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25079354

Citation

Xie, Ying, et al. "Pd-catalyzed [3+2] Cycloaddition of Ketoimines With Alkynes Via Directed Sp³ C-H Bond Activation." Chemical Communications (Cambridge, England), vol. 50, no. 73, 2014, pp. 10699-702.
Xie Y, Chen T, Fu S, et al. Pd-catalyzed [3+2] cycloaddition of ketoimines with alkynes via directed sp³ C-H bond activation. Chem Commun (Camb). 2014;50(73):10699-702.
Xie, Y., Chen, T., Fu, S., Li, X. S., Deng, Y., Jiang, H., & Zeng, W. (2014). Pd-catalyzed [3+2] cycloaddition of ketoimines with alkynes via directed sp³ C-H bond activation. Chemical Communications (Cambridge, England), 50(73), 10699-702. https://doi.org/10.1039/c4cc04676e
Xie Y, et al. Pd-catalyzed [3+2] Cycloaddition of Ketoimines With Alkynes Via Directed Sp³ C-H Bond Activation. Chem Commun (Camb). 2014 Sep 21;50(73):10699-702. PubMed PMID: 25079354.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Pd-catalyzed [3+2] cycloaddition of ketoimines with alkynes via directed sp³ C-H bond activation. AU - Xie,Ying, AU - Chen,Tengfei, AU - Fu,Shaomin, AU - Li,Xing-Shu, AU - Deng,Yuanfu, AU - Jiang,Huanfeng, AU - Zeng,Wei, Y1 - 2014/07/31/ PY - 2014/8/1/entrez PY - 2014/8/1/pubmed PY - 2015/6/2/medline SP - 10699 EP - 702 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 50 IS - 73 N2 - The Pd(II)-catalyzed oxidative [3+2] cycloaddition of N-(2-pyridyl) ketoimines with internal alkynes has been developed. The transformation is tolerant of extensive substitution on halogen, alkene, alkyne, hydroxyl, aryl and acyl groups, and allows facile assembly of multisubstituted pyrroles. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/25079354/Pd_catalyzed_[3+2]_cycloaddition_of_ketoimines_with_alkynes_via_directed_sp³_C_H_bond_activation_ L2 - https://doi.org/10.1039/c4cc04676e DB - PRIME DP - Unbound Medicine ER -