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Rhodium(III)-catalyzed C-H alkynylation of azomethine ylides under mild conditions.
Org Biomol Chem. 2014 Dec 14; 12(46):9329-32.OB

Abstract

Rh(III)-catalyzed efficient C-H alkynylation of azomethine imines with alkynylated hypervalent iodine is developed under mild conditions. A broad scope of azomethine imines and alkyne substrates is established. The azomethine acts as a masked aldehyde and circumvents its poor directing effect.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Zhang X
School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Ji'nan 250353, China.
Qi Z
No affiliation info available
Gao J
No affiliation info available
Li X
No affiliation info available

MeSH

AldehydesAlkynesAzo CompoundsCatalysisIminesIodineMolecular StructureRhodiumStereoisomerismThiosemicarbazones

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25325793

Citation

Zhang, Xueyun, et al. "Rhodium(III)-catalyzed C-H Alkynylation of Azomethine Ylides Under Mild Conditions." Organic & Biomolecular Chemistry, vol. 12, no. 46, 2014, pp. 9329-32.
Zhang X, Qi Z, Gao J, et al. Rhodium(III)-catalyzed C-H alkynylation of azomethine ylides under mild conditions. Org Biomol Chem. 2014;12(46):9329-32.
Zhang, X., Qi, Z., Gao, J., & Li, X. (2014). Rhodium(III)-catalyzed C-H alkynylation of azomethine ylides under mild conditions. Organic & Biomolecular Chemistry, 12(46), 9329-32. https://doi.org/10.1039/c4ob01596g
Zhang X, et al. Rhodium(III)-catalyzed C-H Alkynylation of Azomethine Ylides Under Mild Conditions. Org Biomol Chem. 2014 Dec 14;12(46):9329-32. PubMed PMID: 25325793.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium(III)-catalyzed C-H alkynylation of azomethine ylides under mild conditions. AU - Zhang,Xueyun, AU - Qi,Zisong, AU - Gao,Jian, AU - Li,Xingwei, Y1 - 2014/10/17/ PY - 2014/10/18/entrez PY - 2014/10/18/pubmed PY - 2015/6/30/medline SP - 9329 EP - 32 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 12 IS - 46 N2 - Rh(III)-catalyzed efficient C-H alkynylation of azomethine imines with alkynylated hypervalent iodine is developed under mild conditions. A broad scope of azomethine imines and alkyne substrates is established. The azomethine acts as a masked aldehyde and circumvents its poor directing effect. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/25325793/Rhodium_III__catalyzed_C_H_alkynylation_of_azomethine_ylides_under_mild_conditions_ DB - PRIME DP - Unbound Medicine ER -