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Formation of self-extinguishing flame retardant biobased coating on cotton fabrics via Layer-by-Layer assembly of chitin derivatives.
Carbohydr Polym. 2015 Jan 22; 115:516-24.CP

Abstract

The self-extinguishing coating, consisting of biobased chitin derivatives, phosphorylated chitin and deacetylated chitin (chitosan), was deposited on cotton fabrics via the Layer-by-Layer (LbL) assembled method. The content of phosphorylated chitin prepared on cotton fabrics surface is dependent on the bilayers' number and concentration of phosphorylated chitin. In the vertical flame test, the cotton fabric with 20 bilayers prepared at the high phosphorylated chitin concentration (2 wt%) could extinguish the flame. Microcombustion calorimetry result showed that all coated cotton fabrics showed lower peak heat-release rate and total heat-release values compared with that of the pure one. Thermogravimetric analysis result indicated that thermal and thermal oxidation stability of all coated cotton fabrics were enhanced in the high temperature range (400-700°C). This work provided the flame retardant multilayer films based on fully biobased chitin derivatives on cotton fabrics to enhance its flame retardancy.

Authors+Show Affiliations

State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People's Republic of China; Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute of University of Science and Technology of China, 166 Ren'ai Road, Suzhou, Jiangsu 215123, People's Republic of China.State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People's Republic of China.State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People's Republic of China.State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People's Republic of China. Electronic address: leisong@ustc.edu.cn.State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People's Republic of China; Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute of University of Science and Technology of China, 166 Ren'ai Road, Suzhou, Jiangsu 215123, People's Republic of China. Electronic address: yuanhu@ustc.edu.cn.Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute of University of Science and Technology of China, 166 Ren'ai Road, Suzhou, Jiangsu 215123, People's Republic of China; Department of Building and Construction, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong.

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25439927

Citation

Pan, Haifeng, et al. "Formation of Self-extinguishing Flame Retardant Biobased Coating On Cotton Fabrics Via Layer-by-Layer Assembly of Chitin Derivatives." Carbohydrate Polymers, vol. 115, 2015, pp. 516-24.
Pan H, Wang W, Pan Y, et al. Formation of self-extinguishing flame retardant biobased coating on cotton fabrics via Layer-by-Layer assembly of chitin derivatives. Carbohydr Polym. 2015;115:516-24.
Pan, H., Wang, W., Pan, Y., Song, L., Hu, Y., & Liew, K. M. (2015). Formation of self-extinguishing flame retardant biobased coating on cotton fabrics via Layer-by-Layer assembly of chitin derivatives. Carbohydrate Polymers, 115, 516-24. https://doi.org/10.1016/j.carbpol.2014.08.084
Pan H, et al. Formation of Self-extinguishing Flame Retardant Biobased Coating On Cotton Fabrics Via Layer-by-Layer Assembly of Chitin Derivatives. Carbohydr Polym. 2015 Jan 22;115:516-24. PubMed PMID: 25439927.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Formation of self-extinguishing flame retardant biobased coating on cotton fabrics via Layer-by-Layer assembly of chitin derivatives. AU - Pan,Haifeng, AU - Wang,Wei, AU - Pan,Ying, AU - Song,Lei, AU - Hu,Yuan, AU - Liew,Kim Meow, Y1 - 2014/09/02/ PY - 2014/05/19/received PY - 2014/08/15/revised PY - 2014/08/17/accepted PY - 2014/12/3/entrez PY - 2014/12/3/pubmed PY - 2015/10/27/medline KW - Chitosan KW - Layer-by-Layer assembly method KW - Phosphorylated chitin KW - Self-extinguishing SP - 516 EP - 24 JF - Carbohydrate polymers JO - Carbohydr Polym VL - 115 N2 - The self-extinguishing coating, consisting of biobased chitin derivatives, phosphorylated chitin and deacetylated chitin (chitosan), was deposited on cotton fabrics via the Layer-by-Layer (LbL) assembled method. The content of phosphorylated chitin prepared on cotton fabrics surface is dependent on the bilayers' number and concentration of phosphorylated chitin. In the vertical flame test, the cotton fabric with 20 bilayers prepared at the high phosphorylated chitin concentration (2 wt%) could extinguish the flame. Microcombustion calorimetry result showed that all coated cotton fabrics showed lower peak heat-release rate and total heat-release values compared with that of the pure one. Thermogravimetric analysis result indicated that thermal and thermal oxidation stability of all coated cotton fabrics were enhanced in the high temperature range (400-700°C). This work provided the flame retardant multilayer films based on fully biobased chitin derivatives on cotton fabrics to enhance its flame retardancy. SN - 1879-1344 UR - https://www.unboundmedicine.com/medline/citation/25439927/Formation_of_self_extinguishing_flame_retardant_biobased_coating_on_cotton_fabrics_via_Layer_by_Layer_assembly_of_chitin_derivatives_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0144-8617(14)00860-1 DB - PRIME DP - Unbound Medicine ER -