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Rhodium(III)-catalyzed C-H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles.
Chem Commun (Camb). 2015 Feb 18; 51(14):2925-8.CC

Abstract

Herein we disclose the first example of Rh(iii)-catalyzed intermolecular annulation of indoles with terminal alkynes to give highly efficient one-pot access to privileged carbazoles. The mild reaction features moderate to good yields, exclusive regioselectivity, broad substrate scope, and excellent functional group tolerance.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Jia J
VARI/SIMM Center, Center for Structure and Function of Drug Targets, CAS-Key Laboratory of Receptor Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, P. R. China. yiwei.simm@simm.ac.cn eric.xu@simm.ac.cn.
Shi J
No affiliation info available
Zhou J
No affiliation info available
Liu X
No affiliation info available
Song Y
No affiliation info available
Xu HE
No affiliation info available
Yi W
No affiliation info available

MeSH

AlkynesCarbazolesCarbonCatalysisHydrogenIndolesRhodiumStereoisomerismSubstrate Specificity

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25585938

Citation

Jia, Jinlong, et al. "Rhodium(III)-catalyzed C-H Activation and Intermolecular Annulation With Terminal Alkynes: From Indoles to Carbazoles." Chemical Communications (Cambridge, England), vol. 51, no. 14, 2015, pp. 2925-8.
Jia J, Shi J, Zhou J, et al. Rhodium(III)-catalyzed C-H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles. Chem Commun (Camb). 2015;51(14):2925-8.
Jia, J., Shi, J., Zhou, J., Liu, X., Song, Y., Xu, H. E., & Yi, W. (2015). Rhodium(III)-catalyzed C-H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles. Chemical Communications (Cambridge, England), 51(14), 2925-8. https://doi.org/10.1039/c4cc09823d
Jia J, et al. Rhodium(III)-catalyzed C-H Activation and Intermolecular Annulation With Terminal Alkynes: From Indoles to Carbazoles. Chem Commun (Camb). 2015 Feb 18;51(14):2925-8. PubMed PMID: 25585938.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium(III)-catalyzed C-H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles. AU - Jia,Jinlong, AU - Shi,Jingjing, AU - Zhou,Jie, AU - Liu,Xuelei, AU - Song,Yanling, AU - Xu,H Eric, AU - Yi,Wei, PY - 2015/1/15/entrez PY - 2015/1/15/pubmed PY - 2015/9/18/medline SP - 2925 EP - 8 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 51 IS - 14 N2 - Herein we disclose the first example of Rh(iii)-catalyzed intermolecular annulation of indoles with terminal alkynes to give highly efficient one-pot access to privileged carbazoles. The mild reaction features moderate to good yields, exclusive regioselectivity, broad substrate scope, and excellent functional group tolerance. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/25585938/Rhodium_III__catalyzed_C_H_activation_and_intermolecular_annulation_with_terminal_alkynes:_from_indoles_to_carbazoles_ DB - PRIME DP - Unbound Medicine ER -