Tags

Type your tag names separated by a space and hit enter

Ruthenium(II)-catalyzed C-H activation/alkyne annulation by weak coordination with O2 as the sole oxidant.
Angew Chem Int Ed Engl. 2015 Apr 27; 54(18):5513-7.AC

Abstract

Aerobic oxidative CH functionalizations of weakly coordinating benzoic acids have been accomplished with versatile ruthenium(II) biscarboxylates under ambient oxygen or air. Mechanistic studies identified the key factors controlling the elementary step of the oxidation of the ruthenium(0) complex.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Warratz S
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/
Kornhaaβ C
No affiliation info available
Cajaraville A
No affiliation info available
Niepötter B
No affiliation info available
Stalke D
No affiliation info available
Ackermann L
No affiliation info available

MeSH

AerobiosisAlkenesAlkynesBenzoic AcidCatalysisHydrogen BondingIsocoumarinsMolecular StructureOxidation-ReductionOxygenRuthenium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25737001

Citation

Warratz, Svenja, et al. "Ruthenium(II)-catalyzed C-H Activation/alkyne Annulation By Weak Coordination With O2 as the Sole Oxidant." Angewandte Chemie (International Ed. in English), vol. 54, no. 18, 2015, pp. 5513-7.
Warratz S, Kornhaaβ C, Cajaraville A, et al. Ruthenium(II)-catalyzed C-H activation/alkyne annulation by weak coordination with O2 as the sole oxidant. Angew Chem Int Ed Engl. 2015;54(18):5513-7.
Warratz, S., Kornhaaβ, C., Cajaraville, A., Niepötter, B., Stalke, D., & Ackermann, L. (2015). Ruthenium(II)-catalyzed C-H activation/alkyne annulation by weak coordination with O2 as the sole oxidant. Angewandte Chemie (International Ed. in English), 54(18), 5513-7. https://doi.org/10.1002/anie.201500600
Warratz S, et al. Ruthenium(II)-catalyzed C-H Activation/alkyne Annulation By Weak Coordination With O2 as the Sole Oxidant. Angew Chem Int Ed Engl. 2015 Apr 27;54(18):5513-7. PubMed PMID: 25737001.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ruthenium(II)-catalyzed C-H activation/alkyne annulation by weak coordination with O2 as the sole oxidant. AU - Warratz,Svenja, AU - Kornhaaβ,Christoph, AU - Cajaraville,Ana, AU - Niepötter,Benedikt, AU - Stalke,Dietmar, AU - Ackermann,Lutz, Y1 - 2015/03/03/ PY - 2015/01/21/received PY - 2015/3/5/entrez PY - 2015/3/5/pubmed PY - 2016/1/27/medline KW - CH activation KW - benzoic acids KW - dioxygen KW - oxidation KW - ruthenium SP - 5513 EP - 7 JF - Angewandte Chemie (International ed. in English) JO - Angew Chem Int Ed Engl VL - 54 IS - 18 N2 - Aerobic oxidative CH functionalizations of weakly coordinating benzoic acids have been accomplished with versatile ruthenium(II) biscarboxylates under ambient oxygen or air. Mechanistic studies identified the key factors controlling the elementary step of the oxidation of the ruthenium(0) complex. SN - 1521-3773 UR - https://www.unboundmedicine.com/medline/citation/25737001/Ruthenium_II__catalyzed_C_H_activation/alkyne_annulation_by_weak_coordination_with_O2_as_the_sole_oxidant_ DB - PRIME DP - Unbound Medicine ER -