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Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation.
Chem Commun (Camb). 2015 May 04; 51(36):7685-8.CC

Abstract

We successfully developed rhodium-catalysed synthesis of multi-substituted silylindenes from 2 equivalents of aryl alkynes and 1 equivalent of hydrosilanes in moderate to good yields via C-H bond activation for the first time. The silyl groups of the obtained silylindenes could be converted to several other functional groups.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Sueki S
Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. kuninobu@mol.f.u-tokyo.ac.jp.
Kuninobu Y
No affiliation info available

MeSH

AlkynesCarbonCatalysisHydrogenIndenesMolecular StructureOrganometallic CompoundsOrganosilicon CompoundsRhodiumSilanes

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

25849792

Citation

Sueki, Shunsuke, and Yoichiro Kuninobu. "Rhodium-catalysed Synthesis of Multi-substituted Silylindenes From Aryl Alkynes and Hydrosilanes Via C-H Bond Activation." Chemical Communications (Cambridge, England), vol. 51, no. 36, 2015, pp. 7685-8.
Sueki S, Kuninobu Y. Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation. Chem Commun (Camb). 2015;51(36):7685-8.
Sueki, S., & Kuninobu, Y. (2015). Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation. Chemical Communications (Cambridge, England), 51(36), 7685-8. https://doi.org/10.1039/c5cc01569c
Sueki S, Kuninobu Y. Rhodium-catalysed Synthesis of Multi-substituted Silylindenes From Aryl Alkynes and Hydrosilanes Via C-H Bond Activation. Chem Commun (Camb). 2015 May 4;51(36):7685-8. PubMed PMID: 25849792.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation. AU - Sueki,Shunsuke, AU - Kuninobu,Yoichiro, PY - 2015/4/8/entrez PY - 2015/4/8/pubmed PY - 2016/2/2/medline SP - 7685 EP - 8 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 51 IS - 36 N2 - We successfully developed rhodium-catalysed synthesis of multi-substituted silylindenes from 2 equivalents of aryl alkynes and 1 equivalent of hydrosilanes in moderate to good yields via C-H bond activation for the first time. The silyl groups of the obtained silylindenes could be converted to several other functional groups. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/25849792/Rhodium_catalysed_synthesis_of_multi_substituted_silylindenes_from_aryl_alkynes_and_hydrosilanes_via_C_H_bond_activation_ DB - PRIME DP - Unbound Medicine ER -