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An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin.
Org Biomol Chem. 2015 Sep 07; 13(33):8906-11.OB

Abstract

We report an efficient Mukaiyama-aldol reaction of tryptanthrin with fluorinated enol silyl ethers, which is carried out in methanol without the use of any catalyst. This method is applied to the total synthesis of the difluoro analogues of the natural product Phaitanthrin B.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Liao FM
Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, P. R. China. jzhou@chem.ecnu.edu.cn.
Liu YL
No affiliation info available
Yu JS
No affiliation info available
Zhou F
No affiliation info available
Zhou J
No affiliation info available

MeSH

AldehydesBiological ProductsCatalysisChemistry, OrganicEthersHalogenationMagnetic Resonance SpectroscopyQuinazolinesSilanes

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

26205007

Citation

Liao, Fu-Min, et al. "An Efficient Catalyst-free Mukaiyama-aldol Reaction of Fluorinated Enol Silyl Ethers With Tryptanthrin." Organic & Biomolecular Chemistry, vol. 13, no. 33, 2015, pp. 8906-11.
Liao FM, Liu YL, Yu JS, et al. An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin. Org Biomol Chem. 2015;13(33):8906-11.
Liao, F. M., Liu, Y. L., Yu, J. S., Zhou, F., & Zhou, J. (2015). An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin. Organic & Biomolecular Chemistry, 13(33), 8906-11. https://doi.org/10.1039/c5ob01125f
Liao FM, et al. An Efficient Catalyst-free Mukaiyama-aldol Reaction of Fluorinated Enol Silyl Ethers With Tryptanthrin. Org Biomol Chem. 2015 Sep 7;13(33):8906-11. PubMed PMID: 26205007.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin. AU - Liao,Fu-Min, AU - Liu,Yun-Lin, AU - Yu,Jin-Sheng, AU - Zhou,Feng, AU - Zhou,Jian, PY - 2015/7/25/entrez PY - 2015/7/25/pubmed PY - 2016/5/18/medline SP - 8906 EP - 11 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 13 IS - 33 N2 - We report an efficient Mukaiyama-aldol reaction of tryptanthrin with fluorinated enol silyl ethers, which is carried out in methanol without the use of any catalyst. This method is applied to the total synthesis of the difluoro analogues of the natural product Phaitanthrin B. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/26205007/An_efficient_catalyst_free_Mukaiyama_aldol_reaction_of_fluorinated_enol_silyl_ethers_with_tryptanthrin_ DB - PRIME DP - Unbound Medicine ER -