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Rhodium(III)-catalyzed oxidative bicyclization of 4-arylbut-3-yn-1-amines with internal alkynes through C-H functionalization.
Chem Commun (Camb). 2015 Sep 11; 51(70):13550-3.CC

Abstract

A new Rh(iii)-catalyzed oxidative bicyclization through C-H functionalization is presented. This reaction allows the selective assembly of diverse benzo[g]indoles from 4-arylbut-3-yn-1-amines and internal alkynes via a sequence of aromatic C(sp(2))-H functionalization, cyclodimerization and nucleophilic cyclization.

Authors+Show Affiliations

State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. jhli@hnu.edu.cn.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

26222901

Citation

Pi, Rui, et al. "Rhodium(III)-catalyzed Oxidative Bicyclization of 4-arylbut-3-yn-1-amines With Internal Alkynes Through C-H Functionalization." Chemical Communications (Cambridge, England), vol. 51, no. 70, 2015, pp. 13550-3.
Pi R, Zhou MB, Yang Y, et al. Rhodium(III)-catalyzed oxidative bicyclization of 4-arylbut-3-yn-1-amines with internal alkynes through C-H functionalization. Chem Commun (Camb). 2015;51(70):13550-3.
Pi, R., Zhou, M. B., Yang, Y., Gao, C., Song, R. J., & Li, J. H. (2015). Rhodium(III)-catalyzed oxidative bicyclization of 4-arylbut-3-yn-1-amines with internal alkynes through C-H functionalization. Chemical Communications (Cambridge, England), 51(70), 13550-3. https://doi.org/10.1039/c5cc05093f
Pi R, et al. Rhodium(III)-catalyzed Oxidative Bicyclization of 4-arylbut-3-yn-1-amines With Internal Alkynes Through C-H Functionalization. Chem Commun (Camb). 2015 Sep 11;51(70):13550-3. PubMed PMID: 26222901.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium(III)-catalyzed oxidative bicyclization of 4-arylbut-3-yn-1-amines with internal alkynes through C-H functionalization. AU - Pi,Rui, AU - Zhou,Ming-Bo, AU - Yang,Yuan, AU - Gao,Cai, AU - Song,Ren-Jie, AU - Li,Jin-Heng, PY - 2015/7/30/entrez PY - 2015/7/30/pubmed PY - 2016/6/3/medline SP - 13550 EP - 3 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 51 IS - 70 N2 - A new Rh(iii)-catalyzed oxidative bicyclization through C-H functionalization is presented. This reaction allows the selective assembly of diverse benzo[g]indoles from 4-arylbut-3-yn-1-amines and internal alkynes via a sequence of aromatic C(sp(2))-H functionalization, cyclodimerization and nucleophilic cyclization. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/26222901/Rhodium_III__catalyzed_oxidative_bicyclization_of_4_arylbut_3_yn_1_amines_with_internal_alkynes_through_C_H_functionalization_ L2 - https://doi.org/10.1039/c5cc05093f DB - PRIME DP - Unbound Medicine ER -