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Lattice Breathing Inhibited Layered Vanadium Oxide Ultrathin Nanobelts for Enhanced Sodium Storage.
ACS Appl Mater Interfaces. 2015 Aug 26; 7(33):18211-7.AA

Abstract

Operating as the "rocking-chair" battery, sodium ion battery (SIB) with acceptable high capacity is a very promising energy storage technology. Layered vanadium oxide xerogel exhibits high sodium storage capacity. But it undergoes large lattice breathing during sodiation/desodiation, resulting in fast capacity fading. Herein, we develop a facile hydrothermal method to synthesize iron preintercalated vanadium oxide ultrathin nanobelts (Fe-VOx) with constricted interlayer spacing. Using the Fe-VOx as cathode for SIB, the lattice breathing during sodiation/desodiation is largely inhibited and the interlayer spacing is stabilized for reversible and rapid Na(+) insertion/extraction, displaying enhanced cycling and rate performance. This work presents a new strategy to reduce the lattice breathing of layered materials for enhanced sodium storage through interlayer spacing engineering.

Authors+Show Affiliations

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and §School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology , Wuhan 430070, P. R. China.

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

26258426

Citation

Wei, Qiulong, et al. "Lattice Breathing Inhibited Layered Vanadium Oxide Ultrathin Nanobelts for Enhanced Sodium Storage." ACS Applied Materials & Interfaces, vol. 7, no. 33, 2015, pp. 18211-7.
Wei Q, Jiang Z, Tan S, et al. Lattice Breathing Inhibited Layered Vanadium Oxide Ultrathin Nanobelts for Enhanced Sodium Storage. ACS Appl Mater Interfaces. 2015;7(33):18211-7.
Wei, Q., Jiang, Z., Tan, S., Li, Q., Huang, L., Yan, M., Zhou, L., An, Q., & Mai, L. (2015). Lattice Breathing Inhibited Layered Vanadium Oxide Ultrathin Nanobelts for Enhanced Sodium Storage. ACS Applied Materials & Interfaces, 7(33), 18211-7. https://doi.org/10.1021/acsami.5b06154
Wei Q, et al. Lattice Breathing Inhibited Layered Vanadium Oxide Ultrathin Nanobelts for Enhanced Sodium Storage. ACS Appl Mater Interfaces. 2015 Aug 26;7(33):18211-7. PubMed PMID: 26258426.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Lattice Breathing Inhibited Layered Vanadium Oxide Ultrathin Nanobelts for Enhanced Sodium Storage. AU - Wei,Qiulong, AU - Jiang,Zhouyang, AU - Tan,Shuangshuang, AU - Li,Qidong, AU - Huang,Lei, AU - Yan,Mengyu, AU - Zhou,Liang, AU - An,Qinyou, AU - Mai,Liqiang, Y1 - 2015/08/14/ PY - 2015/8/11/entrez PY - 2015/8/11/pubmed PY - 2015/8/11/medline KW - lattice breathing KW - layered structure KW - nanobelt KW - sodium ion battery KW - vanadium oxide SP - 18211 EP - 7 JF - ACS applied materials & interfaces JO - ACS Appl Mater Interfaces VL - 7 IS - 33 N2 - Operating as the "rocking-chair" battery, sodium ion battery (SIB) with acceptable high capacity is a very promising energy storage technology. Layered vanadium oxide xerogel exhibits high sodium storage capacity. But it undergoes large lattice breathing during sodiation/desodiation, resulting in fast capacity fading. Herein, we develop a facile hydrothermal method to synthesize iron preintercalated vanadium oxide ultrathin nanobelts (Fe-VOx) with constricted interlayer spacing. Using the Fe-VOx as cathode for SIB, the lattice breathing during sodiation/desodiation is largely inhibited and the interlayer spacing is stabilized for reversible and rapid Na(+) insertion/extraction, displaying enhanced cycling and rate performance. This work presents a new strategy to reduce the lattice breathing of layered materials for enhanced sodium storage through interlayer spacing engineering. SN - 1944-8252 UR - https://www.unboundmedicine.com/medline/citation/26258426/Lattice_Breathing_Inhibited_Layered_Vanadium_Oxide_Ultrathin_Nanobelts_for_Enhanced_Sodium_Storage_ L2 - https://dx.doi.org/10.1021/acsami.5b06154 DB - PRIME DP - Unbound Medicine ER -
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