A newly developed molecularly imprinted polymer on the surface of TiO2 for selective extraction of triazine herbicides residues in maize, water, and soil.
Anal Bioanal Chem. 2015 Nov; 407(29):8803-12.AB

Abstract

A new surface molecularly imprinted polymer (MIP) based on nano-TiO2 was developed using propazine (Pro) as a template molecule, ethyleneglycol dimethacrylate (EGDMA) as a crosslinker, methacrylic acid (MAA) as a functional monomer, and 2,2'-azobis (isobutyronitrile) (AIBN) as an initiator. Structures of the newly synthesized surface MIPs were characterized by Fourier transmission infrared spectrometry (FT-IR), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). The MIP had a good adsorption capacity and high recognition selectivity to propazine. Meanwhile, it exhibited a cross-selectivity for simazine (Sim) and atrazine (Atr). The MIPs were used as a solid phase extraction (SPE) material. Concomitant extraction, purification, and determination of three pesticides (Pro, Sim, and Atr) residues in water, soil, and maize plant and grain samples were performed by MIP-SPE coupled with high performance liquid chromatography (HPLC). The highly selective separation and enrichment of Pro, Atr, and Sim from the complex environmental media can be achieved. Thus, the newly developed technique provides an analytical platform to quantify the trace amount of Pro, Sim, and Atr residues in multi environmental media and food source.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Geng HR

Jiangsu Key Laboratory of Pesticide Science, College of Science, Nanjing Agricultural University, Nanjing, 210095, China.

Miao SS

Jiangsu Key Laboratory of Pesticide Science, College of Science, Nanjing Agricultural University, Nanjing, 210095, China. Key Laboratory of Monitoring and Management of Crop Diseases and Pest Insects, Ministry of Agriculture, Nanjing Agricultural University, Nanjing, 210095, China.

Jin SF

Jiangsu Key Laboratory of Pesticide Science, College of Science, Nanjing Agricultural University, Nanjing, 210095, China.

Yang H

Jiangsu Key Laboratory of Pesticide Science, College of Science, Nanjing Agricultural University, Nanjing, 210095, China. hongyang@njau.edu.cn.

MeSH

Environmental PollutantsFood AnalysisHerbicidesLimit of DetectionModels, MolecularMolecular ImprintingPolymersSoilSolid Phase ExtractionTitaniumTriazinesWaterZea mays

Pub Type(s)

Journal Article

Research Support, Non-U.S. Gov't

Validation Study

Language

eng

PubMed ID

26410737

Citation

Geng, Hao Ran, et al. "A Newly Developed Molecularly Imprinted Polymer On the Surface of TiO2 for Selective Extraction of Triazine Herbicides Residues in Maize, Water, and Soil." Analytical and Bioanalytical Chemistry, vol. 407, no. 29, 2015, pp. 8803-12.

Geng HR, Miao SS, Jin SF, et al. A newly developed molecularly imprinted polymer on the surface of TiO2 for selective extraction of triazine herbicides residues in maize, water, and soil. Anal Bioanal Chem. 2015;407(29):8803-12.

Geng, H. R., Miao, S. S., Jin, S. F., & Yang, H. (2015). A newly developed molecularly imprinted polymer on the surface of TiO2 for selective extraction of triazine herbicides residues in maize, water, and soil. Analytical and Bioanalytical Chemistry, 407(29), 8803-12. https://doi.org/10.1007/s00216-015-9039-x

Geng HR, et al. A Newly Developed Molecularly Imprinted Polymer On the Surface of TiO2 for Selective Extraction of Triazine Herbicides Residues in Maize, Water, and Soil. Anal Bioanal Chem. 2015;407(29):8803-12. PubMed PMID: 26410737.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - A newly developed molecularly imprinted polymer on the surface of TiO2 for selective extraction of triazine herbicides residues in maize, water, and soil. AU - Geng,Hao Ran, AU - Miao,Shan Shan, AU - Jin,She Feng, AU - Yang,Hong, Y1 - 2015/09/26/ PY - 2015/06/23/received PY - 2015/09/10/accepted PY - 2015/08/23/revised PY - 2015/9/28/entrez PY - 2015/9/28/pubmed PY - 2016/9/1/medline KW - Environmental monitoring KW - Herbicide KW - Molecularly imprinted polymer KW - Nano-TiO2 KW - Propazine KW - SPE SP - 8803 EP - 12 JF - Analytical and bioanalytical chemistry JO - Anal Bioanal Chem VL - 407 IS - 29 N2 - A new surface molecularly imprinted polymer (MIP) based on nano-TiO2 was developed using propazine (Pro) as a template molecule, ethyleneglycol dimethacrylate (EGDMA) as a crosslinker, methacrylic acid (MAA) as a functional monomer, and 2,2'-azobis (isobutyronitrile) (AIBN) as an initiator. Structures of the newly synthesized surface MIPs were characterized by Fourier transmission infrared spectrometry (FT-IR), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). The MIP had a good adsorption capacity and high recognition selectivity to propazine. Meanwhile, it exhibited a cross-selectivity for simazine (Sim) and atrazine (Atr). The MIPs were used as a solid phase extraction (SPE) material. Concomitant extraction, purification, and determination of three pesticides (Pro, Sim, and Atr) residues in water, soil, and maize plant and grain samples were performed by MIP-SPE coupled with high performance liquid chromatography (HPLC). The highly selective separation and enrichment of Pro, Atr, and Sim from the complex environmental media can be achieved. Thus, the newly developed technique provides an analytical platform to quantify the trace amount of Pro, Sim, and Atr residues in multi environmental media and food source. SN - 1618-2650 UR - https://www.unboundmedicine.com/medline/citation/26410737/A_newly_developed_molecularly_imprinted_polymer_on_the_surface_of_TiO2_for_selective_extraction_of_triazine_herbicides_residues_in_maize_water_and_soil_ DB - PRIME DP - Unbound Medicine ER -

Tags

A newly developed molecularly imprinted polymer on the surface of TiO2 for selective extraction of triazine herbicides residues in maize, water, and soil.Anal Bioanal Chem. 2015 Nov; 407(29):8803-12.AB