Tags

Type your tag names separated by a space and hit enter

Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones To Form Conjugated Ynones and Disubstituted Alkynes.
Org Lett. 2015 Nov 06; 17(21):5504-7.OL

Abstract

A Rh-catalyzed controlled decarbonylation of alkynyl α-diones is described. By using different ligand and solvent combinations, mono- and double-decarbonylation can be selectively achieved to give conjugated ynones and disubstituted alkynes, respectively. A fundamental study on catalytic activation of unstrained C-C bonds under nonoxidative conditions is presented.

Authors+Show Affiliations

Department of Chemistry, The University of Texas at Austin , 101 East 24th Street, A5300, Austin, Texas 78712, United States.Department of Chemistry, The University of Texas at Austin , 101 East 24th Street, A5300, Austin, Texas 78712, United States.

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

26503477

Citation

Whittaker, Rachel E., and Guangbin Dong. "Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones to Form Conjugated Ynones and Disubstituted Alkynes." Organic Letters, vol. 17, no. 21, 2015, pp. 5504-7.
Whittaker RE, Dong G. Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones To Form Conjugated Ynones and Disubstituted Alkynes. Org Lett. 2015;17(21):5504-7.
Whittaker, R. E., & Dong, G. (2015). Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones To Form Conjugated Ynones and Disubstituted Alkynes. Organic Letters, 17(21), 5504-7. https://doi.org/10.1021/acs.orglett.5b02911
Whittaker RE, Dong G. Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones to Form Conjugated Ynones and Disubstituted Alkynes. Org Lett. 2015 Nov 6;17(21):5504-7. PubMed PMID: 26503477.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones To Form Conjugated Ynones and Disubstituted Alkynes. AU - Whittaker,Rachel E, AU - Dong,Guangbin, Y1 - 2015/10/27/ PY - 2015/10/28/entrez PY - 2015/10/28/pubmed PY - 2016/3/10/medline SP - 5504 EP - 7 JF - Organic letters JO - Org Lett VL - 17 IS - 21 N2 - A Rh-catalyzed controlled decarbonylation of alkynyl α-diones is described. By using different ligand and solvent combinations, mono- and double-decarbonylation can be selectively achieved to give conjugated ynones and disubstituted alkynes, respectively. A fundamental study on catalytic activation of unstrained C-C bonds under nonoxidative conditions is presented. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/26503477/Controlled_Rh_Catalyzed_Mono__and_Double_decarbonylation_of_Alkynyl_α_Diones_To_Form_Conjugated_Ynones_and_Disubstituted_Alkynes_ L2 - https://doi.org/10.1021/acs.orglett.5b02911 DB - PRIME DP - Unbound Medicine ER -