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Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C-H activation.
Chem Commun (Camb). 2016 Feb 18; 52(14):2872-84.CC

Abstract

The purpose of this article is to give a brief review of weak chelation-assistance as a powerful means for the rhodium-catalyzed annulation of arenes with alkynes. The use of commonly occurring functional groups (e.g., ketones, aldehydes, carboxylic acids and alcohols) as the directing groups enriches the versatility of auxiliary ligands and extends the scope of products. This short article offers an overview on emerging procedures, highlights their advantages and limitations, and covers the latest progress in the rapid synthesis of organic functional materials and natural products.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Yang Y
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn.
Li K
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn.
Cheng Y
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn.
Wan D
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn.
Li M
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn.
You J
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn.

MeSH

AlkynesCarbonCatalysisChelating AgentsHydrogenRhodium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

26757884

Citation

Yang, Yudong, et al. "Rhodium-catalyzed Annulation of Arenes With Alkynes Through Weak Chelation-assisted C-H Activation." Chemical Communications (Cambridge, England), vol. 52, no. 14, 2016, pp. 2872-84.
Yang Y, Li K, Cheng Y, et al. Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C-H activation. Chem Commun (Camb). 2016;52(14):2872-84.
Yang, Y., Li, K., Cheng, Y., Wan, D., Li, M., & You, J. (2016). Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C-H activation. Chemical Communications (Cambridge, England), 52(14), 2872-84. https://doi.org/10.1039/c5cc09180b
Yang Y, et al. Rhodium-catalyzed Annulation of Arenes With Alkynes Through Weak Chelation-assisted C-H Activation. Chem Commun (Camb). 2016 Feb 18;52(14):2872-84. PubMed PMID: 26757884.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C-H activation. AU - Yang,Yudong, AU - Li,Kaizhi, AU - Cheng,Yangyang, AU - Wan,Danyang, AU - Li,Mingliang, AU - You,Jingsong, PY - 2016/1/14/entrez PY - 2016/1/14/pubmed PY - 2016/11/12/medline SP - 2872 EP - 84 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 52 IS - 14 N2 - The purpose of this article is to give a brief review of weak chelation-assistance as a powerful means for the rhodium-catalyzed annulation of arenes with alkynes. The use of commonly occurring functional groups (e.g., ketones, aldehydes, carboxylic acids and alcohols) as the directing groups enriches the versatility of auxiliary ligands and extends the scope of products. This short article offers an overview on emerging procedures, highlights their advantages and limitations, and covers the latest progress in the rapid synthesis of organic functional materials and natural products. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/26757884/Rhodium_catalyzed_annulation_of_arenes_with_alkynes_through_weak_chelation_assisted_C_H_activation_ DB - PRIME DP - Unbound Medicine ER -