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Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides.
Chemistry. 2016 Dec 05; 22(49):17542-17546.C

Abstract

A palladium-catalyzed direct C-arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides.

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Publisher Full Text (DOI)

Authors+Show Affiliations

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.

Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

27782302

Citation

Lu, Ju-You, et al. "Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium With (Hetero)Aryl Halides." Chemistry (Weinheim an Der Bergstrasse, Germany), vol. 22, no. 49, 2016, pp. 17542-17546.

Lu JY, Wan H, Zhang J, et al. Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides. Chemistry. 2016;22(49):17542-17546.

Lu, J. Y., Wan, H., Zhang, J., Wang, Z., Li, Y., Du, Y., Li, C., Liu, Z. T., Liu, Z. W., & Lu, J. (2016). Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides. Chemistry (Weinheim an Der Bergstrasse, Germany), 22(49), 17542-17546. https://doi.org/10.1002/chem.201603967

Lu JY, et al. Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium With (Hetero)Aryl Halides. Chemistry. 2016 Dec 5;22(49):17542-17546. PubMed PMID: 27782302.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides. AU - Lu,Ju-You, AU - Wan,Hong, AU - Zhang,Jianwei, AU - Wang,Zhixuan, AU - Li,Yang, AU - Du,Yongmei, AU - Li,Chunying, AU - Liu,Zhao-Tie, AU - Liu,Zhong-Wen, AU - Lu,Jian, Y1 - 2016/10/26/ PY - 2016/08/20/received PY - 2016/10/27/pubmed PY - 2016/10/27/medline PY - 2016/10/27/entrez KW - C(cage)−C(sp2) formation KW - carboranyllithium KW - cross-coupling KW - direct C-arylation KW - palladium SP - 17542 EP - 17546 JF - Chemistry (Weinheim an der Bergstrasse, Germany) JO - Chemistry VL - 22 IS - 49 N2 - A palladium-catalyzed direct C-arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides. SN - 1521-3765 UR - https://www.unboundmedicine.com/medline/citation/27782302/Palladium_Catalyzed_Direct_Cross_Coupling_of_Carboranyllithium_with__Hetero_Aryl_Halides_ DB - PRIME DP - Unbound Medicine ER -