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Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of β-Naphthols.
Angew Chem Int Ed Engl. 2016 11 21; 55(48):15137-15141.AC

Abstract

The first Pd0 -catalyzed intermolecular arylative dearomatization of β-naphthols with aryl halides is described. It was found that Q-Phos could facilitate the palladium-catalyzed cross-coupling-type dearomatization of β-naphthols, while avoiding O-arylation, to construct 2-naphthalenones in excellent yields and with high chemoselectivity.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Xu RQ
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032, China.
Yang P
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032, China.
Tu HF
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032, China.
Wang SG
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032, China.
You SL
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032, China.

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

27791314

Citation

Xu, Ren-Qi, et al. "Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of Β-Naphthols." Angewandte Chemie (International Ed. in English), vol. 55, no. 48, 2016, pp. 15137-15141.
Xu RQ, Yang P, Tu HF, et al. Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of β-Naphthols. Angew Chem Int Ed Engl. 2016;55(48):15137-15141.
Xu, R. Q., Yang, P., Tu, H. F., Wang, S. G., & You, S. L. (2016). Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of β-Naphthols. Angewandte Chemie (International Ed. in English), 55(48), 15137-15141. https://doi.org/10.1002/anie.201608724
Xu RQ, et al. Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of Β-Naphthols. Angew Chem Int Ed Engl. 2016 11 21;55(48):15137-15141. PubMed PMID: 27791314.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of β-Naphthols. AU - Xu,Ren-Qi, AU - Yang,Ping, AU - Tu,Hang-Fei, AU - Wang,Shou-Guo, AU - You,Shu-Li, Y1 - 2016/10/28/ PY - 2016/09/06/received PY - 2016/10/30/pubmed PY - 2016/10/30/medline PY - 2016/10/30/entrez KW - cross-coupling KW - dearomatization KW - homogeneous catalysis KW - naphthol KW - palladium SP - 15137 EP - 15141 JF - Angewandte Chemie (International ed. in English) JO - Angew Chem Int Ed Engl VL - 55 IS - 48 N2 - The first Pd0 -catalyzed intermolecular arylative dearomatization of β-naphthols with aryl halides is described. It was found that Q-Phos could facilitate the palladium-catalyzed cross-coupling-type dearomatization of β-naphthols, while avoiding O-arylation, to construct 2-naphthalenones in excellent yields and with high chemoselectivity. SN - 1521-3773 UR - https://www.unboundmedicine.com/medline/citation/27791314/Palladium_0__Catalyzed_Intermolecular_Arylative_Dearomatization_of_β_Naphthols_ DB - PRIME DP - Unbound Medicine ER -