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Ultralong Sb2Se3 Nanowire-Based Free-Standing Membrane Anode for Lithium/Sodium Ion Batteries.
ACS Appl Mater Interfaces. 2016 Dec 28; 8(51):35219-35226.AA

Abstract

Metal chalcogenides have emerged as promising anode materials for lithium ion batteries (LIBs) and sodium ion batteries (SIBs). Herein, a free-standing membrane based on ultralong Sb2Se3 nanowires has been successfully fabricated via a facile hydrothermal synthesis combined with a subsequent vacuum filtration treatment. The as-achieved free-standing membrane constructed by pure Sb2Se3 nanowires exhibits good flexibility and integrity. Meanwhile, we investigate the lithium and sodium storage behavior of the Sb2Se3 nanowire-based free-standing membrane. When applied as the anode for LIBs, it delivers a reversible capacity of 614 mA h g-1 at 100 mA g-1, maintaining 584 mA h g-1 after 50 cycles. When applied as the anode for SIBs, it delivers a reversible capacity of 360 mA h g-1 at 100 mA g-1, retaining 289 mA h g-1 after 50 cycles. Such difference in electrochemical performance can be attributed to the more complex sodiation process relative to the corresponding lithiation process. This work may provide insight on developing Sb2Se3-based anode materials for high-performance LIBs or SIBs.

Authors+Show Affiliations

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology , Wuhan 430070, People's Republic of China.Metz National School of Engineering, University of Lorraine , Metz 57000, France.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology , Wuhan 430070, People's Republic of China. Department of Mathematics and Physics, Luoyang Institute of Science and Technology , Luoyang 471023, People's Republic of China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology , Wuhan 430070, People's Republic of China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology , Wuhan 430070, People's Republic of China.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology , Wuhan 430070, People's Republic of China.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

27959503

Citation

Luo, Wen, et al. "Ultralong Sb2Se3 Nanowire-Based Free-Standing Membrane Anode for Lithium/Sodium Ion Batteries." ACS Applied Materials & Interfaces, vol. 8, no. 51, 2016, pp. 35219-35226.
Luo W, Calas A, Tang C, et al. Ultralong Sb2Se3 Nanowire-Based Free-Standing Membrane Anode for Lithium/Sodium Ion Batteries. ACS Appl Mater Interfaces. 2016;8(51):35219-35226.
Luo, W., Calas, A., Tang, C., Li, F., Zhou, L., & Mai, L. (2016). Ultralong Sb2Se3 Nanowire-Based Free-Standing Membrane Anode for Lithium/Sodium Ion Batteries. ACS Applied Materials & Interfaces, 8(51), 35219-35226. https://doi.org/10.1021/acsami.6b11544
Luo W, et al. Ultralong Sb2Se3 Nanowire-Based Free-Standing Membrane Anode for Lithium/Sodium Ion Batteries. ACS Appl Mater Interfaces. 2016 Dec 28;8(51):35219-35226. PubMed PMID: 27959503.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ultralong Sb2Se3 Nanowire-Based Free-Standing Membrane Anode for Lithium/Sodium Ion Batteries. AU - Luo,Wen, AU - Calas,Armand, AU - Tang,Chunjuan, AU - Li,Feng, AU - Zhou,Liang, AU - Mai,Liqiang, Y1 - 2016/12/13/ PY - 2016/12/14/pubmed PY - 2016/12/14/medline PY - 2016/12/14/entrez KW - anode KW - antimony triselenide (Sb2Se3) KW - free-standing membrane KW - lithium ion battery KW - nanowire KW - sodium ion battery SP - 35219 EP - 35226 JF - ACS applied materials & interfaces JO - ACS Appl Mater Interfaces VL - 8 IS - 51 N2 - Metal chalcogenides have emerged as promising anode materials for lithium ion batteries (LIBs) and sodium ion batteries (SIBs). Herein, a free-standing membrane based on ultralong Sb2Se3 nanowires has been successfully fabricated via a facile hydrothermal synthesis combined with a subsequent vacuum filtration treatment. The as-achieved free-standing membrane constructed by pure Sb2Se3 nanowires exhibits good flexibility and integrity. Meanwhile, we investigate the lithium and sodium storage behavior of the Sb2Se3 nanowire-based free-standing membrane. When applied as the anode for LIBs, it delivers a reversible capacity of 614 mA h g-1 at 100 mA g-1, maintaining 584 mA h g-1 after 50 cycles. When applied as the anode for SIBs, it delivers a reversible capacity of 360 mA h g-1 at 100 mA g-1, retaining 289 mA h g-1 after 50 cycles. Such difference in electrochemical performance can be attributed to the more complex sodiation process relative to the corresponding lithiation process. This work may provide insight on developing Sb2Se3-based anode materials for high-performance LIBs or SIBs. SN - 1944-8252 UR - https://www.unboundmedicine.com/medline/citation/27959503/Ultralong_Sb2Se3_Nanowire_Based_Free_Standing_Membrane_Anode_for_Lithium/Sodium_Ion_Batteries_ L2 - https://dx.doi.org/10.1021/acsami.6b11544 DB - PRIME DP - Unbound Medicine ER -
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