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Efficient synthesis of carborane azo derivatives and their reactivity.
Dalton Trans. 2017 Jan 31; 46(5):1585-1592.DT

Abstract

An iridium(iii)-catalyzed C-N-bond-forming direct synthesis of carborane azo derivatives was developed. The reaction of o-carborane monocarboxylate with aryldiazonium salt in the presence of a catalytic amount of [Cp*IrCl2]2 and NaOAc in CH3CN at 80 °C gave the corresponding carborane azo derivative in good yield. A series of cyclometalated iridium/rhodium complexes that contain Cp*M-B (M = Ir, Rh) bonds, and are stabilised by the intramolecular coordination of nitrogen donors, were successfully isolated and structurally characterised.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Gao Y
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China. yfhan1980@fudan.edu.cn gxjin@fudan.edu.cn.
Lin YJ
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China. yfhan1980@fudan.edu.cn gxjin@fudan.edu.cn.
Han YF
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China. yfhan1980@fudan.edu.cn gxjin@fudan.edu.cn.
Jin GX
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China. yfhan1980@fudan.edu.cn gxjin@fudan.edu.cn.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

28091648

Citation

Gao, Yang, et al. "Efficient Synthesis of Carborane Azo Derivatives and Their Reactivity." Dalton Transactions (Cambridge, England : 2003), vol. 46, no. 5, 2017, pp. 1585-1592.
Gao Y, Lin YJ, Han YF, et al. Efficient synthesis of carborane azo derivatives and their reactivity. Dalton Trans. 2017;46(5):1585-1592.
Gao, Y., Lin, Y. J., Han, Y. F., & Jin, G. X. (2017). Efficient synthesis of carborane azo derivatives and their reactivity. Dalton Transactions (Cambridge, England : 2003), 46(5), 1585-1592. https://doi.org/10.1039/c6dt04550b
Gao Y, et al. Efficient Synthesis of Carborane Azo Derivatives and Their Reactivity. Dalton Trans. 2017 Jan 31;46(5):1585-1592. PubMed PMID: 28091648.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Efficient synthesis of carborane azo derivatives and their reactivity. AU - Gao,Yang, AU - Lin,Yue-Jian, AU - Han,Ying-Feng, AU - Jin,Guo-Xin, PY - 2017/1/17/pubmed PY - 2017/1/17/medline PY - 2017/1/17/entrez SP - 1585 EP - 1592 JF - Dalton transactions (Cambridge, England : 2003) JO - Dalton Trans VL - 46 IS - 5 N2 - An iridium(iii)-catalyzed C-N-bond-forming direct synthesis of carborane azo derivatives was developed. The reaction of o-carborane monocarboxylate with aryldiazonium salt in the presence of a catalytic amount of [Cp*IrCl2]2 and NaOAc in CH3CN at 80 °C gave the corresponding carborane azo derivative in good yield. A series of cyclometalated iridium/rhodium complexes that contain Cp*M-B (M = Ir, Rh) bonds, and are stabilised by the intramolecular coordination of nitrogen donors, were successfully isolated and structurally characterised. SN - 1477-9234 UR - https://www.unboundmedicine.com/medline/citation/28091648/Efficient_synthesis_of_carborane_azo_derivatives_and_their_reactivity_ DB - PRIME DP - Unbound Medicine ER -
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