TY - JOUR T1 - Simple, cost-effective and sensitive liquid chromatography diode array detector method for simultaneous determination of eight sulfonylurea herbicides in soya milk samples. AU - Rejczak,Tomasz, AU - Tuzimski,Tomasz, Y1 - 2016/10/12/ PY - 2016/08/14/received PY - 2016/09/30/revised PY - 2016/10/10/accepted PY - 2017/3/19/entrez PY - 2017/3/21/pubmed PY - 2017/4/5/medline KW - HPLC–DAD analysis KW - Matrix effect KW - QuEChERS KW - Soya milk KW - Sulfonylurea herbicides KW - Zirconium-dioxide based sorbent SP - 56 EP - 65 JF - Journal of chromatography. A JO - J Chromatogr A VL - 1473 N2 - In this study authors propose a simple, cost-effective and sensitive liquid chromatography diode array detector (HPLC-DAD) method for the simultaneous determination of eight sulfonylurea herbicides (oxasulfuron, metsulfuron-methyl, triasulfuron, rimsulfuron, chlorsulfuron, mesosulfuron-methyl, amidosulfuron and bensulfuron-methyl) in soya milk samples. QuEChERS-based extraction procedure presents good performance for all of the analytes with recoveries in the range of 61-108% and relative standard deviations (RSD%) less than 15%. No significant matrix effect was observed thanks to application of effective zirconium-dioxide based sorbent (Z-Sep). Method LOQs for all investigated analytes were set at satisfactory low value of 10ngmL-1 of food product. The procedure was evaluated in terms of natural samples analysis. Chlorsulfuron was determined at concentration of 14.2ngmL-1 of soya milk product, which was qualitatively confirmed via LC coupled with tandem mass spectrometry (LC-MS/MS). The most important steps of procedure optimization are presented. SN - 1873-3778 UR - https://www.unboundmedicine.com/medline/citation/28314393/Simple_cost_effective_and_sensitive_liquid_chromatography_diode_array_detector_method_for_simultaneous_determination_of_eight_sulfonylurea_herbicides_in_soya_milk_samples_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0021-9673(16)31355-3 DB - PRIME DP - Unbound Medicine ER -