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Mesoporous Mn2O3/reduced graphene oxide (rGO) composite with enhanced electrochemical performance for Li-ion battery.
Dalton Trans. 2017 Aug 14; 46(30):9777-9783.DT

Abstract

Transition metal oxides are the most promising candidates in low-cost and eco-friendly energy storage/conversion applications. Herein, bare Mn2O3 and a Mn2O3/reduced graphene oxide (rGO) composite have been synthesized by a facile chemical co-precipitation and subsequent annealing procedure. The synthesized Mn2O3/rGO composite exhibits a porous microcube structure formed with several interconnected particles. The porous Mn2O3/rGO composite, with high surface area and increased conductivity, facilited the charge transfer to enhance the overall electrochemical performance when applied as an anode material in Li-ion batteries. The porous Mn2O3/rGO composite exhibits a highly reversible lithium storage capacity of 1015 mA h g-1 at a rate of 0.5 C (230 mA g-1) during 130 cycles with excellent cycling stability and rate capability. The superior electrochemical performance results mainly due to the combined effect of rGO and Mn2O3, which offers high conductivity, faster Li+ ion transfer, and enhanced structural stability. The material synthesis strategy presented in this study is simple, cost-effective and scalable, which can open new avenues for large-scale applications of composites of graphene and other transition metal oxides.

Authors+Show Affiliations

Department of Energy Science and Technology, Energy and Environment Fusion Technology Center, Myongji University, Nam-dong, Cheoin-gu, Yongin-si, Republic of Korea. jgseo@mju.ac.kr.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

28548664

Citation

Jadhav, Harsharaj S., et al. "Mesoporous Mn2O3/reduced Graphene Oxide (rGO) Composite With Enhanced Electrochemical Performance for Li-ion Battery." Dalton Transactions (Cambridge, England : 2003), vol. 46, no. 30, 2017, pp. 9777-9783.
Jadhav HS, Thorat GM, Kale BB, et al. Mesoporous Mn2O3/reduced graphene oxide (rGO) composite with enhanced electrochemical performance for Li-ion battery. Dalton Trans. 2017;46(30):9777-9783.
Jadhav, H. S., Thorat, G. M., Kale, B. B., & Seo, J. G. (2017). Mesoporous Mn2O3/reduced graphene oxide (rGO) composite with enhanced electrochemical performance for Li-ion battery. Dalton Transactions (Cambridge, England : 2003), 46(30), 9777-9783. https://doi.org/10.1039/c7dt01424d
Jadhav HS, et al. Mesoporous Mn2O3/reduced Graphene Oxide (rGO) Composite With Enhanced Electrochemical Performance for Li-ion Battery. Dalton Trans. 2017 Aug 14;46(30):9777-9783. PubMed PMID: 28548664.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Mesoporous Mn2O3/reduced graphene oxide (rGO) composite with enhanced electrochemical performance for Li-ion battery. AU - Jadhav,Harsharaj S, AU - Thorat,Gaurav M, AU - Kale,Bharat B, AU - Seo,Jeong Gil, Y1 - 2017/05/26/ PY - 2017/5/27/pubmed PY - 2017/5/27/medline PY - 2017/5/27/entrez SP - 9777 EP - 9783 JF - Dalton transactions (Cambridge, England : 2003) JO - Dalton Trans VL - 46 IS - 30 N2 - Transition metal oxides are the most promising candidates in low-cost and eco-friendly energy storage/conversion applications. Herein, bare Mn2O3 and a Mn2O3/reduced graphene oxide (rGO) composite have been synthesized by a facile chemical co-precipitation and subsequent annealing procedure. The synthesized Mn2O3/rGO composite exhibits a porous microcube structure formed with several interconnected particles. The porous Mn2O3/rGO composite, with high surface area and increased conductivity, facilited the charge transfer to enhance the overall electrochemical performance when applied as an anode material in Li-ion batteries. The porous Mn2O3/rGO composite exhibits a highly reversible lithium storage capacity of 1015 mA h g-1 at a rate of 0.5 C (230 mA g-1) during 130 cycles with excellent cycling stability and rate capability. The superior electrochemical performance results mainly due to the combined effect of rGO and Mn2O3, which offers high conductivity, faster Li+ ion transfer, and enhanced structural stability. The material synthesis strategy presented in this study is simple, cost-effective and scalable, which can open new avenues for large-scale applications of composites of graphene and other transition metal oxides. SN - 1477-9234 UR - https://www.unboundmedicine.com/medline/citation/28548664/Mesoporous_Mn2O3/reduced_graphene_oxide__rGO__composite_with_enhanced_electrochemical_performance_for_Li_ion_battery_ L2 - https://doi.org/10.1039/c7dt01424d DB - PRIME DP - Unbound Medicine ER -
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