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Sb2O3 Nanoparticles Anchored on Graphene Sheets via Alcohol Dissolution-Reprecipitation Method for Excellent Lithium-Storage Properties.
ACS Appl Mater Interfaces. 2017 Oct 11; 9(40):34927-34936.AA

Abstract

Sb2O3 nanoparticles are uniformly anchored on reduced graphene oxide (rGO) sheets via a facile and ecofriendly route based on the alcohol dissolution-reprecipitation method. Such obtained Sb2O3/rGO composite demonstrates a highly reversible specific capacity (1355 mA h g-1 at 100 mA g-1), good rate capability, and superior life cycle (525 mA h g-1 after 700 cycles at 600 mA g-1) when used an anode electrode for lithium-ion batteries (LIBs). The outstanding electrochemical properties of Sb2O3/rGO composite could be attributed to its unique structure in which the strong electronic coupling effect between Sb2O3 and rGO leads to an enhanced electronic conductivity, structure stability, and electrochemical activity during reversible conversion-alloying reactions. Also, these findings are helpful in both developing novel high-performance electrodes for LIBs and synthesizing functional materials in an ecofriendly and economical way.

Authors+Show Affiliations

Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University , Lanzhou 730070, Gansu, P. R. China.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

28933532

Citation

Zhou, Xiaozhong, et al. "Sb2O3 Nanoparticles Anchored On Graphene Sheets Via Alcohol Dissolution-Reprecipitation Method for Excellent Lithium-Storage Properties." ACS Applied Materials & Interfaces, vol. 9, no. 40, 2017, pp. 34927-34936.
Zhou X, Zhang Z, Lu X, et al. Sb2O3 Nanoparticles Anchored on Graphene Sheets via Alcohol Dissolution-Reprecipitation Method for Excellent Lithium-Storage Properties. ACS Appl Mater Interfaces. 2017;9(40):34927-34936.
Zhou, X., Zhang, Z., Lu, X., Lv, X., Ma, G., Wang, Q., & Lei, Z. (2017). Sb2O3 Nanoparticles Anchored on Graphene Sheets via Alcohol Dissolution-Reprecipitation Method for Excellent Lithium-Storage Properties. ACS Applied Materials & Interfaces, 9(40), 34927-34936. https://doi.org/10.1021/acsami.7b10107
Zhou X, et al. Sb2O3 Nanoparticles Anchored On Graphene Sheets Via Alcohol Dissolution-Reprecipitation Method for Excellent Lithium-Storage Properties. ACS Appl Mater Interfaces. 2017 Oct 11;9(40):34927-34936. PubMed PMID: 28933532.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Sb2O3 Nanoparticles Anchored on Graphene Sheets via Alcohol Dissolution-Reprecipitation Method for Excellent Lithium-Storage Properties. AU - Zhou,Xiaozhong, AU - Zhang,Zhengfeng, AU - Lu,Xiaofang, AU - Lv,Xueyan, AU - Ma,Guofu, AU - Wang,Qingtao, AU - Lei,Ziqiang, Y1 - 2017/09/27/ PY - 2017/9/22/pubmed PY - 2017/9/22/medline PY - 2017/9/22/entrez KW - Sb2O3/rGO composite KW - alcohol dissolution−reprecipitation method KW - electronic coupling effect KW - lithium-ion batteries KW - lithium-storage properties SP - 34927 EP - 34936 JF - ACS applied materials & interfaces JO - ACS Appl Mater Interfaces VL - 9 IS - 40 N2 - Sb2O3 nanoparticles are uniformly anchored on reduced graphene oxide (rGO) sheets via a facile and ecofriendly route based on the alcohol dissolution-reprecipitation method. Such obtained Sb2O3/rGO composite demonstrates a highly reversible specific capacity (1355 mA h g-1 at 100 mA g-1), good rate capability, and superior life cycle (525 mA h g-1 after 700 cycles at 600 mA g-1) when used an anode electrode for lithium-ion batteries (LIBs). The outstanding electrochemical properties of Sb2O3/rGO composite could be attributed to its unique structure in which the strong electronic coupling effect between Sb2O3 and rGO leads to an enhanced electronic conductivity, structure stability, and electrochemical activity during reversible conversion-alloying reactions. Also, these findings are helpful in both developing novel high-performance electrodes for LIBs and synthesizing functional materials in an ecofriendly and economical way. SN - 1944-8252 UR - https://www.unboundmedicine.com/medline/citation/28933532/Sb2O3_Nanoparticles_Anchored_on_Graphene_Sheets_via_Alcohol_Dissolution_Reprecipitation_Method_for_Excellent_Lithium_Storage_Properties_ L2 - https://doi.org/10.1021/acsami.7b10107 DB - PRIME DP - Unbound Medicine ER -
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