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Light-induced alterations of pineapple (Ananas comosus [L.] Merr.) juice volatiles during accelerated ageing and mass spectrometric studies into their precursors.
Food Res Int. 2017 10; 100(Pt 3):366-374.FR

Abstract

Alterations of volatiles during accelerated light-induced ageing of pineapple juice were assessed by HS-SPME-GC-MS in a non-targeted profiling analysis over a 16-week period. Multivariate statistics permitted to reveal substantial chemical markers generally describing the effect of light storage. Volatiles generated comprised phenylpropenes, carbonyls, 2-methylthiophene, toluene, and furfural, while concentrations of methyl and ethyl esters, terpenes, and furanones decreased. In addition, the qualitative composition of phenolic compounds and glycoside-bound volatiles in selected samples was characterized by HPLC-DAD-ESI-MSn as well as HR-ESI-MS. The fresh juice contained unique pineapple metabolites such as S-p-coumaryl, S-coniferyl, S-sinapylglutathione, and structurally related derivatives. Among others, the presence of p-coumaroyl, feruloyl, and caffeoylisocitrate as well as three 4-hydroxy-2,5-dimethyl-3(2H)-furanone glycosides in pineapples could be substantiated by the HR-ESI-MS experiment. Mass spectrometric assignments of selected metabolites are presented, and putative linkages between volatiles and their precursors are established.

Authors+Show Affiliations

Institute of Food Science and Biotechnology, Chair Plant Foodstuff Technology and Analysis, University of Hohenheim, Garbenstrasse 25, 70599 Stuttgart, Germany. Electronic address: christof.steingass@uni-hohenheim.de.Institute of Food Science and Biotechnology, Chair Plant Foodstuff Technology and Analysis, University of Hohenheim, Garbenstrasse 25, 70599 Stuttgart, Germany.Institute of Food Science and Biotechnology, Chair Plant Foodstuff Technology and Analysis, University of Hohenheim, Garbenstrasse 25, 70599 Stuttgart, Germany.Institute of Food Science and Biotechnology, Chair Plant Foodstuff Technology and Analysis, University of Hohenheim, Garbenstrasse 25, 70599 Stuttgart, Germany; Biological Science Department, Faculty of Science, King Abdulaziz University, P.O. Box 80257, Jeddah 21589, Saudi Arabia.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

28964359

Citation

Steingass, Christof Björn, et al. "Light-induced Alterations of Pineapple (Ananas Comosus [L.] Merr.) Juice Volatiles During Accelerated Ageing and Mass Spectrometric Studies Into Their Precursors." Food Research International (Ottawa, Ont.), vol. 100, no. Pt 3, 2017, pp. 366-374.
Steingass CB, Glock MP, Lieb VM, et al. Light-induced alterations of pineapple (Ananas comosus [L.] Merr.) juice volatiles during accelerated ageing and mass spectrometric studies into their precursors. Food Res Int. 2017;100(Pt 3):366-374.
Steingass, C. B., Glock, M. P., Lieb, V. M., & Carle, R. (2017). Light-induced alterations of pineapple (Ananas comosus [L.] Merr.) juice volatiles during accelerated ageing and mass spectrometric studies into their precursors. Food Research International (Ottawa, Ont.), 100(Pt 3), 366-374. https://doi.org/10.1016/j.foodres.2017.06.030
Steingass CB, et al. Light-induced Alterations of Pineapple (Ananas Comosus [L.] Merr.) Juice Volatiles During Accelerated Ageing and Mass Spectrometric Studies Into Their Precursors. Food Res Int. 2017;100(Pt 3):366-374. PubMed PMID: 28964359.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Light-induced alterations of pineapple (Ananas comosus [L.] Merr.) juice volatiles during accelerated ageing and mass spectrometric studies into their precursors. AU - Steingass,Christof Björn, AU - Glock,Mona Pia, AU - Lieb,Veronika Maria, AU - Carle,Reinhold, Y1 - 2017/06/19/ PY - 2017/03/29/received PY - 2017/06/09/revised PY - 2017/06/17/accepted PY - 2017/10/2/entrez PY - 2017/10/2/pubmed PY - 2019/7/10/medline KW - HDMF precursors KW - High-resolution mass spectrometry KW - Light-induced volatiles KW - Phenolic compounds KW - Phenylpropenes SP - 366 EP - 374 JF - Food research international (Ottawa, Ont.) JO - Food Res Int VL - 100 IS - Pt 3 N2 - Alterations of volatiles during accelerated light-induced ageing of pineapple juice were assessed by HS-SPME-GC-MS in a non-targeted profiling analysis over a 16-week period. Multivariate statistics permitted to reveal substantial chemical markers generally describing the effect of light storage. Volatiles generated comprised phenylpropenes, carbonyls, 2-methylthiophene, toluene, and furfural, while concentrations of methyl and ethyl esters, terpenes, and furanones decreased. In addition, the qualitative composition of phenolic compounds and glycoside-bound volatiles in selected samples was characterized by HPLC-DAD-ESI-MSn as well as HR-ESI-MS. The fresh juice contained unique pineapple metabolites such as S-p-coumaryl, S-coniferyl, S-sinapylglutathione, and structurally related derivatives. Among others, the presence of p-coumaroyl, feruloyl, and caffeoylisocitrate as well as three 4-hydroxy-2,5-dimethyl-3(2H)-furanone glycosides in pineapples could be substantiated by the HR-ESI-MS experiment. Mass spectrometric assignments of selected metabolites are presented, and putative linkages between volatiles and their precursors are established. SN - 1873-7145 UR - https://www.unboundmedicine.com/medline/citation/28964359/Light_induced_alterations_of_pineapple__Ananas_comosus_[L_]_Merr___juice_volatiles_during_accelerated_ageing_and_mass_spectrometric_studies_into_their_precursors_ DB - PRIME DP - Unbound Medicine ER -