A rapid and simple HPLC-FLD screening method with QuEChERS as the sample treatment for the simultaneous monitoring of nine bisphenols in milk.
Food Chem. 2018 Apr 01; 244:371-377.FC

Abstract

A specific, precise and accurate high performance liquid chromatographic (HPLC) analytical method with a fluorescence detector (FLD) was established for the simultaneous determination of nine bisphenols (BPs) in milk samples. Samples were extracted ultrasonically with acetonitrile and cleaned using the QuEChERS technique. Under the optimized conditions, good linearity was obtained for the nine BPs and the correlation coefficients (R2) ranged from 0.9942 to 0.9997. Recovery values for the nine bisphenols in spiked samples were 75.82-93.86% with intra-day and inter-day relative standard deviations (RSDs) from 2.6 to 11.1%. The limits of detection (LODs) and quantification (LOQs) were 1.0-3.1 μg/kg and 3.5-9.8 μg/kg, respectively. The results demonstrated clearly that the approach developed provides reliable, simple, rapid and environmentally-friendly quantification and identification of nine bisphenols in a fatty matrix and could be used for monitoring bisphenols in milk.

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Authors+Show Affiliations

Xiong L

Lanzhou Institute of Husbandry and Pharmaceutical Sciences, Chinese Academy of Agricultural Sciences, Lanzhou 730050 Gansu, China; Laboratory of Quality & Safety Risk Assessment for Livestock Product (Lanzhou), Ministry of Agriculture, Lanzhou 730050 Gansu, China. Electronic address: xionglin807@sina.com.

Yan P

Chu M

Lanzhou Institute of Husbandry and Pharmaceutical Sciences, Chinese Academy of Agricultural Sciences, Lanzhou 730050 Gansu, China; Key Laboratory for Yak Genetics, Breeding & Reproduction Engineering of Gansu Province, Lanzhou 730050 Gansu, China.

Gao YQ

Li WH

Yang XL

MeSH

AnimalsBenzhydryl CompoundsChromatography, High Pressure LiquidFluorescenceFood AnalysisFood ContaminationLimit of DetectionMilkPhenols

Pub Type(s)

Journal Article

Language

eng

PubMed ID

29120796

Citation

Xiong, Lin, et al. "A Rapid and Simple HPLC-FLD Screening Method With QuEChERS as the Sample Treatment for the Simultaneous Monitoring of Nine Bisphenols in Milk." Food Chemistry, vol. 244, 2018, pp. 371-377.

Xiong L, Yan P, Chu M, et al. A rapid and simple HPLC-FLD screening method with QuEChERS as the sample treatment for the simultaneous monitoring of nine bisphenols in milk. Food Chem. 2018;244:371-377.

Xiong, L., Yan, P., Chu, M., Gao, Y. Q., Li, W. H., & Yang, X. L. (2018). A rapid and simple HPLC-FLD screening method with QuEChERS as the sample treatment for the simultaneous monitoring of nine bisphenols in milk. Food Chemistry, 244, 371-377. https://doi.org/10.1016/j.foodchem.2017.10.030

Xiong L, et al. A Rapid and Simple HPLC-FLD Screening Method With QuEChERS as the Sample Treatment for the Simultaneous Monitoring of Nine Bisphenols in Milk. Food Chem. 2018 Apr 1;244:371-377. PubMed PMID: 29120796.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - A rapid and simple HPLC-FLD screening method with QuEChERS as the sample treatment for the simultaneous monitoring of nine bisphenols in milk. AU - Xiong,Lin, AU - Yan,Ping, AU - Chu,Min, AU - Gao,Ya-Qin, AU - Li,Wei-Hong, AU - Yang,Xiao-Ling, Y1 - 2017/10/10/ PY - 2016/10/19/received PY - 2017/08/23/revised PY - 2017/10/08/accepted PY - 2017/11/10/entrez PY - 2017/11/10/pubmed PY - 2018/8/14/medline KW - Bisphenol A (PubChem CID: 6623) KW - Bisphenol A Bis (2, 3-dihydroxyprophy) Ether (PubChem CID: 110678) KW - Bisphenol A diglycidyl ether (PubChem CID: 2286) KW - Bisphenol B (PubChem CID: 66166) KW - Bisphenol C (PubChem CID: 6620) KW - Bisphenol E (PubChem CID: 608116) KW - Bisphenol F Diglycidyl Ether (PubChem CID: 91511) KW - Bisphenol F Glycidyl 2,3-Dihydroxypropyl Ether (PubChem CID: 71360307) KW - Bisphenol F bis (2,3-dihydroxyprophy) Ether (PubChem CID: 3928015) KW - Bisphenols KW - HPLC–FLD KW - Milk KW - QuEChERS SP - 371 EP - 377 JF - Food chemistry JO - Food Chem VL - 244 N2 - A specific, precise and accurate high performance liquid chromatographic (HPLC) analytical method with a fluorescence detector (FLD) was established for the simultaneous determination of nine bisphenols (BPs) in milk samples. Samples were extracted ultrasonically with acetonitrile and cleaned using the QuEChERS technique. Under the optimized conditions, good linearity was obtained for the nine BPs and the correlation coefficients (R2) ranged from 0.9942 to 0.9997. Recovery values for the nine bisphenols in spiked samples were 75.82-93.86% with intra-day and inter-day relative standard deviations (RSDs) from 2.6 to 11.1%. The limits of detection (LODs) and quantification (LOQs) were 1.0-3.1 μg/kg and 3.5-9.8 μg/kg, respectively. The results demonstrated clearly that the approach developed provides reliable, simple, rapid and environmentally-friendly quantification and identification of nine bisphenols in a fatty matrix and could be used for monitoring bisphenols in milk. SN - 1873-7072 UR - https://www.unboundmedicine.com/medline/citation/29120796/A_rapid_and_simple_HPLC_FLD_screening_method_with_QuEChERS_as_the_sample_treatment_for_the_simultaneous_monitoring_of_nine_bisphenols_in_milk_ DB - PRIME DP - Unbound Medicine ER -

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A rapid and simple HPLC-FLD screening method with QuEChERS as the sample treatment for the simultaneous monitoring of nine bisphenols in milk.Food Chem. 2018 Apr 01; 244:371-377.FC