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Determination of nine bisphenols in sewage and sludge using dummy molecularly imprinted solid-phase extraction coupled with liquid chromatography tandem mass spectrometry.
J Chromatogr A. 2018 Jun 01; 1552:10-16.JC

Abstract

This paper describes the determination of bisphenol A (BPA), bisphenol S (BPS), bisphenol F (BPF), bisphenol E (BPE), bisphenol B (BPB), bisphenol AF (BPAF), bisphenol AP (BPAP), bisphenol Z (BPZ) and tetrabromobisphenol A (TBBPA) in sewage and sludge samples. A highly class-selective dummy molecularly imprinted polymer was used for solid phase extraction (SPE) and clean-up of the samples. Bisphenols was quantified by high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The developed method had acceptable recoveries (43.6-101%), precision (RSDs: 1.5-15%) and matrix effects (-6.7 to 28%). The method limits of quantitation (MLOQs) for nine bisphenols in sewage and sludge samples were 0.0007-16.3 ng L-1 and 0.0004-8.28 ng g-1 dry weight (dw), respectively. The method was applied to a survey of a municipal wastewater treatment plant (WWTP) in Dalian. All of the tested bisphenols, except BPB and BPZ, were presented in the analyzed samples. BPA, BPS, and BPF with the concentrations 412, 109 and 66.4 ng L-1 in the WWTP influent, respectively, were the predominant bisphenols. The results demonstrated that BPS and BPF have become the most frequently used substitutes of BPA.

Authors+Show Affiliations

Department of Chemistry, Lishui University, Lishui 32300, China. Electronic address: sxl2015@lsu.edu.cn.CAS Key Laboratory of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.Department of Chemistry, Lishui University, Lishui 32300, China.CAS Key Laboratory of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.Medical School of Ningbo University, Ningbo 315211, China.Department of Chemistry, Lishui University, Lishui 32300, China.Department of Chemistry, Lishui University, Lishui 32300, China.CAS Key Laboratory of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.School of Environmental Science and Engineering, Chang'an University, Xi'an 710054, China.CAS Key Laboratory of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China. Electronic address: chenjp@dicp.ac.cn.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

29678407

Citation

Sun, Xiaoli, et al. "Determination of Nine Bisphenols in Sewage and Sludge Using Dummy Molecularly Imprinted Solid-phase Extraction Coupled With Liquid Chromatography Tandem Mass Spectrometry." Journal of Chromatography. A, vol. 1552, 2018, pp. 10-16.
Sun X, Peng J, Wang M, et al. Determination of nine bisphenols in sewage and sludge using dummy molecularly imprinted solid-phase extraction coupled with liquid chromatography tandem mass spectrometry. J Chromatogr A. 2018;1552:10-16.
Sun, X., Peng, J., Wang, M., Wang, J., Tang, C., Yang, L., Lei, H., Li, F., Wang, X., & Chen, J. (2018). Determination of nine bisphenols in sewage and sludge using dummy molecularly imprinted solid-phase extraction coupled with liquid chromatography tandem mass spectrometry. Journal of Chromatography. A, 1552, 10-16. https://doi.org/10.1016/j.chroma.2018.04.004
Sun X, et al. Determination of Nine Bisphenols in Sewage and Sludge Using Dummy Molecularly Imprinted Solid-phase Extraction Coupled With Liquid Chromatography Tandem Mass Spectrometry. J Chromatogr A. 2018 Jun 1;1552:10-16. PubMed PMID: 29678407.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Determination of nine bisphenols in sewage and sludge using dummy molecularly imprinted solid-phase extraction coupled with liquid chromatography tandem mass spectrometry. AU - Sun,Xiaoli, AU - Peng,Junyu, AU - Wang,Muhua, AU - Wang,Jincheng, AU - Tang,Chunlan, AU - Yang,Luoxing, AU - Lei,Hua, AU - Li,Fang, AU - Wang,Xueli, AU - Chen,Jiping, Y1 - 2018/04/03/ PY - 2017/10/11/received PY - 2018/03/29/revised PY - 2018/04/01/accepted PY - 2018/4/22/pubmed PY - 2018/6/7/medline PY - 2018/4/22/entrez KW - Bisphenols KW - Dummy molecularly imprinted polymer KW - HPLC–MS/MS KW - Matrix effect KW - SPE SP - 10 EP - 16 JF - Journal of chromatography. A JO - J Chromatogr A VL - 1552 N2 - This paper describes the determination of bisphenol A (BPA), bisphenol S (BPS), bisphenol F (BPF), bisphenol E (BPE), bisphenol B (BPB), bisphenol AF (BPAF), bisphenol AP (BPAP), bisphenol Z (BPZ) and tetrabromobisphenol A (TBBPA) in sewage and sludge samples. A highly class-selective dummy molecularly imprinted polymer was used for solid phase extraction (SPE) and clean-up of the samples. Bisphenols was quantified by high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The developed method had acceptable recoveries (43.6-101%), precision (RSDs: 1.5-15%) and matrix effects (-6.7 to 28%). The method limits of quantitation (MLOQs) for nine bisphenols in sewage and sludge samples were 0.0007-16.3 ng L-1 and 0.0004-8.28 ng g-1 dry weight (dw), respectively. The method was applied to a survey of a municipal wastewater treatment plant (WWTP) in Dalian. All of the tested bisphenols, except BPB and BPZ, were presented in the analyzed samples. BPA, BPS, and BPF with the concentrations 412, 109 and 66.4 ng L-1 in the WWTP influent, respectively, were the predominant bisphenols. The results demonstrated that BPS and BPF have become the most frequently used substitutes of BPA. SN - 1873-3778 UR - https://www.unboundmedicine.com/medline/citation/29678407/Determination_of_nine_bisphenols_in_sewage_and_sludge_using_dummy_molecularly_imprinted_solid_phase_extraction_coupled_with_liquid_chromatography_tandem_mass_spectrometry_ DB - PRIME DP - Unbound Medicine ER -