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Degradation of Acid Orange 7 by peroxymonosulfate activated with the recyclable nanocomposites of g-C3N4 modified magnetic carbon.
Chemosphere. 2018 Aug; 205:297-307.C

Abstract

Carbon-based catalysts have attracted high attention since they are greener and cheaper, while magnetic nanomaterials are very useful in environmental application because of the easy recovery and operation given by the magnetic separability. Therefore, graphitic carbon nitride modified magnetic carbon nanocomposites Fe3O4@C/g-C3N4 was prepared herein for the first time as a new carbon-based catalyst for the activation of peroxymonosulfate (PMS). The catalytic properties of Fe3O4@C/g-C3N4 in activating PMS for the degradation of Acid Orange 7 (AO 7), a model organic pollutant, were investigated. AO 7 degradation efficiency was significantly enhanced after modification of Fe3O4@C with g-C3N4, and the composite Fe3O4@C/g-C3N4 from loading of 5 wt% g-C3N4 and calcined at 300 °C for 30 min exhibited the best performance. AO 7 could be efficiently decolorized using the "Fe3O4@C/C3N4 (5%) + PSM" system within the pH range of 2-6, and 97% of AO 7 could be removed in 20 min without pH adjustment (pH = 4). Radical quenching and EPR studies confirmed that both sulfate and hydroxyl radicals produced from PMS activation were the active species responsible for the oxidation of AO 7. The degradation mechanism was suggested based on the experimental results and XPS analyses. It was proposed that the CO groups on the carbon surface of Fe3O4@C rather than the CO in g-C3N4 played a key role as the active sites for PMS activation. The catalyst was magnetically separable and displayed good stability and reusability, thus providing a potentially green catalyst for sustainable remediation of organic pollutants.

Authors+Show Affiliations

School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 430200, China.School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 430200, China.School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 430200, China.Engineering Research Centre for Cleaner Production of Textile Printing and Dyeing, Ministry of Education, Wuhan, 430200, China.Key Laboratory of Catalysis and Materials Sciences of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, Wuhan, 430073, China.School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 430200, China; Engineering Research Centre for Cleaner Production of Textile Printing and Dyeing, Ministry of Education, Wuhan, 430200, China. Electronic address: yingjiecai@wtu.edu.cn.School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 430200, China; Engineering Research Centre for Cleaner Production of Textile Printing and Dyeing, Ministry of Education, Wuhan, 430200, China. Electronic address: qiang_wang@wtu.edu.cn.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

29704837

Citation

Guo, Furong, et al. "Degradation of Acid Orange 7 By Peroxymonosulfate Activated With the Recyclable Nanocomposites of g-C3N4 Modified Magnetic Carbon." Chemosphere, vol. 205, 2018, pp. 297-307.
Guo F, Lu J, Liu Q, et al. Degradation of Acid Orange 7 by peroxymonosulfate activated with the recyclable nanocomposites of g-C3N4 modified magnetic carbon. Chemosphere. 2018;205:297-307.
Guo, F., Lu, J., Liu, Q., Zhang, P., Zhang, A., Cai, Y., & Wang, Q. (2018). Degradation of Acid Orange 7 by peroxymonosulfate activated with the recyclable nanocomposites of g-C3N4 modified magnetic carbon. Chemosphere, 205, 297-307. https://doi.org/10.1016/j.chemosphere.2018.04.139
Guo F, et al. Degradation of Acid Orange 7 By Peroxymonosulfate Activated With the Recyclable Nanocomposites of g-C3N4 Modified Magnetic Carbon. Chemosphere. 2018;205:297-307. PubMed PMID: 29704837.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Degradation of Acid Orange 7 by peroxymonosulfate activated with the recyclable nanocomposites of g-C3N4 modified magnetic carbon. AU - Guo,Furong, AU - Lu,Jiahua, AU - Liu,Qing, AU - Zhang,Ping, AU - Zhang,Aiqing, AU - Cai,Yingjie, AU - Wang,Qiang, Y1 - 2018/04/23/ PY - 2018/01/14/received PY - 2018/03/25/revised PY - 2018/04/21/accepted PY - 2018/4/29/pubmed PY - 2018/8/18/medline PY - 2018/4/29/entrez KW - Advanced oxidation process KW - Dye degradation KW - Graphitic carbon nitride KW - Magnetic carbon KW - Peroxymonosulfate SP - 297 EP - 307 JF - Chemosphere JO - Chemosphere VL - 205 N2 - Carbon-based catalysts have attracted high attention since they are greener and cheaper, while magnetic nanomaterials are very useful in environmental application because of the easy recovery and operation given by the magnetic separability. Therefore, graphitic carbon nitride modified magnetic carbon nanocomposites Fe3O4@C/g-C3N4 was prepared herein for the first time as a new carbon-based catalyst for the activation of peroxymonosulfate (PMS). The catalytic properties of Fe3O4@C/g-C3N4 in activating PMS for the degradation of Acid Orange 7 (AO 7), a model organic pollutant, were investigated. AO 7 degradation efficiency was significantly enhanced after modification of Fe3O4@C with g-C3N4, and the composite Fe3O4@C/g-C3N4 from loading of 5 wt% g-C3N4 and calcined at 300 °C for 30 min exhibited the best performance. AO 7 could be efficiently decolorized using the "Fe3O4@C/C3N4 (5%) + PSM" system within the pH range of 2-6, and 97% of AO 7 could be removed in 20 min without pH adjustment (pH = 4). Radical quenching and EPR studies confirmed that both sulfate and hydroxyl radicals produced from PMS activation were the active species responsible for the oxidation of AO 7. The degradation mechanism was suggested based on the experimental results and XPS analyses. It was proposed that the CO groups on the carbon surface of Fe3O4@C rather than the CO in g-C3N4 played a key role as the active sites for PMS activation. The catalyst was magnetically separable and displayed good stability and reusability, thus providing a potentially green catalyst for sustainable remediation of organic pollutants. SN - 1879-1298 UR - https://www.unboundmedicine.com/medline/citation/29704837/Degradation_of_Acid_Orange_7_by_peroxymonosulfate_activated_with_the_recyclable_nanocomposites_of_g_C3N4_modified_magnetic_carbon_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0045-6535(18)30789-6 DB - PRIME DP - Unbound Medicine ER -