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Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks through a Surfactant-Assisted Method.
Adv Mater 2018; 30(26):e1707234AM

Abstract

During the last decade, the synthesis and application of metal-organic framework (MOF) nanosheets has received growing interest, showing unique performances for different technological applications. Despite the potential of this type of nanolamellar materials, the synthetic routes developed so far are restricted to MOFs possessing layered structures, limiting further development in this field. Here, a bottom-up surfactant-assisted synthetic approach is presented for the fabrication of nanosheets of various nonlayered MOFs, broadening the scope of MOF nanosheets application. Surfactant-assisted preorganization of the metallic precursor prior to MOF synthesis enables the manufacture of nonlayered Al-containing MOF lamellae. These MOF nanosheets are shown to exhibit a superior performance over other crystal morphologies for both chemical sensing and gas separation. As revealed by electron microscopy and diffraction, this superior performance arises from the shorter diffusion pathway in the MOF nanosheets, whose 1D channels are oriented along the shortest particle dimension.

Authors+Show Affiliations

King Abdullah University of Science and Technology, KAUST Catalysis Center, Advanced Catalytic Materials, Thuwal, 23955, Saudi Arabia. Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands.Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, 259 East Ave, NY, 14850, USA.Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands.Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands.Servicios Científico Técnicos, Universidad de Oviedo, Oviedo, 33006, Spain.King Abdullah University of Science and Technology, Functional Materials Design, Advanced Membranes & Porous Materials Center, Thuwal, 23955, Saudi Arabia.King Abdullah University of Science and Technology, KAUST Catalysis Center, Advanced Catalytic Materials, Thuwal, 23955, Saudi Arabia.Heterogene Reaktionen, Max-Planck-Institut für Chemische Engergiekonversion, Stifstrasse 34-36, D-45470, Mülheim an der Ruhr, Germany.Department of Biomedical Engineering, University of Groningen and University Medical Center Groningen, Antonius Deusinglaan 1, 9713 AV, Groningen, The Netherlands.Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P. O. Box 513, 5600 MB, Eindhoven, The Netherlands.Inorganic Chemistry and Catalysis group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.King Abdullah University of Science and Technology, Functional Materials Design, Advanced Membranes & Porous Materials Center, Thuwal, 23955, Saudi Arabia.Laboratory of Organic Chemistry, Wageningen University, Stippeneng 4, 6708 WE, Wageningen, The Netherlands.Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands.Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands.Inorganic Chemistry and Catalysis group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.King Abdullah University of Science and Technology, KAUST Catalysis Center, Advanced Catalytic Materials, Thuwal, 23955, Saudi Arabia. Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

29774609

Citation

Pustovarenko, Alexey, et al. "Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks Through a Surfactant-Assisted Method." Advanced Materials (Deerfield Beach, Fla.), vol. 30, no. 26, 2018, pp. e1707234.
Pustovarenko A, Goesten MG, Sachdeva S, et al. Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks through a Surfactant-Assisted Method. Adv Mater Weinheim. 2018;30(26):e1707234.
Pustovarenko, A., Goesten, M. G., Sachdeva, S., Shan, M., Amghouz, Z., Belmabkhout, Y., ... Gascon, J. (2018). Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks through a Surfactant-Assisted Method. Advanced Materials (Deerfield Beach, Fla.), 30(26), pp. e1707234. doi:10.1002/adma.201707234.
Pustovarenko A, et al. Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks Through a Surfactant-Assisted Method. Adv Mater Weinheim. 2018;30(26):e1707234. PubMed PMID: 29774609.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks through a Surfactant-Assisted Method. AU - Pustovarenko,Alexey, AU - Goesten,Maarten G, AU - Sachdeva,Sumit, AU - Shan,Meixia, AU - Amghouz,Zakariae, AU - Belmabkhout,Youssef, AU - Dikhtiarenko,Alla, AU - Rodenas,Tania, AU - Keskin,Damla, AU - Voets,Ilja K, AU - Weckhuysen,Bert M, AU - Eddaoudi,Mohamed, AU - de Smet,Louis C P M, AU - Sudhölter,Ernst J R, AU - Kapteijn,Freek, AU - Seoane,Beatriz, AU - Gascon,Jorge, Y1 - 2018/05/17/ PY - 2017/12/12/received PY - 2018/03/22/revised PY - 2018/5/19/pubmed PY - 2018/5/19/medline PY - 2018/5/19/entrez KW - chemical sensing KW - crystal design KW - gas separation KW - metal-organic framework nanolamellae KW - molecular recognition SP - e1707234 EP - e1707234 JF - Advanced materials (Deerfield Beach, Fla.) JO - Adv. Mater. Weinheim VL - 30 IS - 26 N2 - During the last decade, the synthesis and application of metal-organic framework (MOF) nanosheets has received growing interest, showing unique performances for different technological applications. Despite the potential of this type of nanolamellar materials, the synthetic routes developed so far are restricted to MOFs possessing layered structures, limiting further development in this field. Here, a bottom-up surfactant-assisted synthetic approach is presented for the fabrication of nanosheets of various nonlayered MOFs, broadening the scope of MOF nanosheets application. Surfactant-assisted preorganization of the metallic precursor prior to MOF synthesis enables the manufacture of nonlayered Al-containing MOF lamellae. These MOF nanosheets are shown to exhibit a superior performance over other crystal morphologies for both chemical sensing and gas separation. As revealed by electron microscopy and diffraction, this superior performance arises from the shorter diffusion pathway in the MOF nanosheets, whose 1D channels are oriented along the shortest particle dimension. SN - 1521-4095 UR - https://www.unboundmedicine.com/medline/citation/29774609/Nanosheets_of_Nonlayered_Aluminum_Metal_Organic_Frameworks_through_a_Surfactant_Assisted_Method_ L2 - https://doi.org/10.1002/adma.201707234 DB - PRIME DP - Unbound Medicine ER -