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Effect of dual modification on properties of biodegradable crosslinked-oxidized starch and oxidized-crosslinked starch films.
Int J Biol Macromol. 2018 Dec; 120(Pt A):1240-1246.IJ

Abstract

Due to poor properties of biodegradable native starch (NS) film; in this work, dual-modified starch films i.e. crosslinked-oxidized starch (C-OS) and oxidized-crosslinked starch (O-CS) films were prepared and compared to single-modified starch i.e. crosslinked starch (CS) and oxidized starch (OS) films. All modified starch films were oxidized and crosslinked using hydrogen peroxide and boric acid by casting technique. Degree of crystallinity and swelling behavior of both dual-modified starch films were found to decrease. Moreover, O-CS film showed smoother fractured morphology than C-OS and NS films. Both C-OS and O-CS films presented not only high stress at maximum load and Young's modulus but also high strain at maximum load, as compared to single-modified film. Furthermore, water vapor permeability, thermal property and biodegradability of all modified films were also studied.

Authors+Show Affiliations

Department of Chemistry, Faculty of Science, King Mongkut's Institute of Technology Ladkrabang (KMITL), Bangkok 10520, Thailand.Department of Chemistry, Faculty of Science, King Mongkut's Institute of Technology Ladkrabang (KMITL), Bangkok 10520, Thailand; Advanced Materials Research Unit, Faculty of Science, King Mongkut's Institute of Technology Ladkrabang (KMITL), Bangkok 10520, Thailand. Electronic address: jutarat.si@kmitl.ac.th.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

30171956

Citation

Tanetrungroj, Yossathorn, and Jutarat Prachayawarakorn. "Effect of Dual Modification On Properties of Biodegradable Crosslinked-oxidized Starch and Oxidized-crosslinked Starch Films." International Journal of Biological Macromolecules, vol. 120, no. Pt A, 2018, pp. 1240-1246.
Tanetrungroj Y, Prachayawarakorn J. Effect of dual modification on properties of biodegradable crosslinked-oxidized starch and oxidized-crosslinked starch films. Int J Biol Macromol. 2018;120(Pt A):1240-1246.
Tanetrungroj, Y., & Prachayawarakorn, J. (2018). Effect of dual modification on properties of biodegradable crosslinked-oxidized starch and oxidized-crosslinked starch films. International Journal of Biological Macromolecules, 120(Pt A), 1240-1246. https://doi.org/10.1016/j.ijbiomac.2018.08.137
Tanetrungroj Y, Prachayawarakorn J. Effect of Dual Modification On Properties of Biodegradable Crosslinked-oxidized Starch and Oxidized-crosslinked Starch Films. Int J Biol Macromol. 2018;120(Pt A):1240-1246. PubMed PMID: 30171956.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Effect of dual modification on properties of biodegradable crosslinked-oxidized starch and oxidized-crosslinked starch films. AU - Tanetrungroj,Yossathorn, AU - Prachayawarakorn,Jutarat, Y1 - 2018/08/29/ PY - 2018/05/28/received PY - 2018/07/19/revised PY - 2018/08/26/accepted PY - 2018/9/2/pubmed PY - 2019/1/5/medline PY - 2018/9/2/entrez KW - Crosslinked starch KW - Dual-modification KW - Oxidized starch SP - 1240 EP - 1246 JF - International journal of biological macromolecules JO - Int J Biol Macromol VL - 120 IS - Pt A N2 - Due to poor properties of biodegradable native starch (NS) film; in this work, dual-modified starch films i.e. crosslinked-oxidized starch (C-OS) and oxidized-crosslinked starch (O-CS) films were prepared and compared to single-modified starch i.e. crosslinked starch (CS) and oxidized starch (OS) films. All modified starch films were oxidized and crosslinked using hydrogen peroxide and boric acid by casting technique. Degree of crystallinity and swelling behavior of both dual-modified starch films were found to decrease. Moreover, O-CS film showed smoother fractured morphology than C-OS and NS films. Both C-OS and O-CS films presented not only high stress at maximum load and Young's modulus but also high strain at maximum load, as compared to single-modified film. Furthermore, water vapor permeability, thermal property and biodegradability of all modified films were also studied. SN - 1879-0003 UR - https://www.unboundmedicine.com/medline/citation/30171956/Effect_of_dual_modification_on_properties_of_biodegradable_crosslinked_oxidized_starch_and_oxidized_crosslinked_starch_films_ DB - PRIME DP - Unbound Medicine ER -