Tags

Type your tag names separated by a space and hit enter

Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries.
Nanomicro Lett. 2018; 10(1):12.NL

Abstract

Hierarchical Sb2S3 hollow microspheres assembled by nanowires have been successfully synthesized by a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated by X-ray diffraction, focused-ion beam-scanning electron microscopy dual-beam system, and transmission electron microscopy. When used as the anode material for lithium-ion batteries, Sb2S3 hollow microspheres manifest excellent rate property and enhanced lithium-storage capability and can deliver a discharge capacity of 674 mAh g-1 at a current density of 200 mA g-1 after 50 cycles. Even at a high current density of 5000 mA g-1, a discharge capacity of 541 mAh g-1 is achieved. Sb2S3 hollow microspheres also display a prominent sodium-storage capacity and maintain a reversible discharge capacity of 384 mAh g-1 at a current density of 200 mA g-1 after 50 cycles. The remarkable lithium/sodium-storage property may be attributed to the synergetic effect of its nanometer size and three-dimensional hierarchical architecture, and the outstanding stability property is attributed to the sufficient interior void space, which can buffer the volume expansion.

Authors+Show Affiliations

1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China. 2Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.1National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, 411105 People's Republic of China.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

30393661

Citation

Xie, Jianjun, et al. "Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries." Nano-micro Letters, vol. 10, no. 1, 2018, p. 12.
Xie J, Liu L, Xia J, et al. Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries. Nano-micro letters. 2018;10(1):12.
Xie, J., Liu, L., Xia, J., Zhang, Y., Li, M., Ouyang, Y., Nie, S., & Wang, X. (2018). Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries. Nano-micro Letters, 10(1), 12. https://doi.org/10.1007/s40820-017-0165-1
Xie J, et al. Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries. Nano-micro letters. 2018;10(1):12. PubMed PMID: 30393661.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries. AU - Xie,Jianjun, AU - Liu,Li, AU - Xia,Jing, AU - Zhang,Yue, AU - Li,Min, AU - Ouyang,Yan, AU - Nie,Su, AU - Wang,Xianyou, Y1 - 2017/10/31/ PY - 2017/08/30/received PY - 2017/09/28/accepted PY - 2018/11/6/entrez PY - 2018/11/6/pubmed PY - 2018/11/6/medline KW - Anode material KW - Hollow microspheres KW - Lithium-ion batteries KW - Sb2S3 KW - Sodium-storage property SP - 12 EP - 12 JF - Nano-micro letters VL - 10 IS - 1 N2 - Hierarchical Sb2S3 hollow microspheres assembled by nanowires have been successfully synthesized by a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated by X-ray diffraction, focused-ion beam-scanning electron microscopy dual-beam system, and transmission electron microscopy. When used as the anode material for lithium-ion batteries, Sb2S3 hollow microspheres manifest excellent rate property and enhanced lithium-storage capability and can deliver a discharge capacity of 674 mAh g-1 at a current density of 200 mA g-1 after 50 cycles. Even at a high current density of 5000 mA g-1, a discharge capacity of 541 mAh g-1 is achieved. Sb2S3 hollow microspheres also display a prominent sodium-storage capacity and maintain a reversible discharge capacity of 384 mAh g-1 at a current density of 200 mA g-1 after 50 cycles. The remarkable lithium/sodium-storage property may be attributed to the synergetic effect of its nanometer size and three-dimensional hierarchical architecture, and the outstanding stability property is attributed to the sufficient interior void space, which can buffer the volume expansion. SN - 2150-5551 UR - https://www.unboundmedicine.com/medline/citation/30393661/Template_Free_Synthesis_of_Sb2S3_Hollow_Microspheres_as_Anode_Materials_for_Lithium_Ion_and_Sodium_Ion_Batteries_ L2 - https://www.ncbi.nlm.nih.gov/pmc/articles/pmid/30393661/ DB - PRIME DP - Unbound Medicine ER -
Try the Free App:
Prime PubMed app for iOS iPhone iPad
Prime PubMed app for Android
Prime PubMed is provided
free to individuals by:
Unbound Medicine.