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Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries.
ACS Appl Mater Interfaces. 2019 Aug 28; 11(34):30858-30864.AA

Abstract

Red phosphorus (P) has recently gained wide attention because of the high theoretical capacity of 2596 mA h/g, which has been regarded as promising anode material for lithium-ion batteries (LIBs). However, the actual application of red P in LIBs is hampered by the huge expansion of volume and low electronic conductivity. Herein, we design a kind of red phosphorus/crumpled nitrogen-doped graphene (P/CNG) nanocomposites with high capacity density and great rate performance as anode material for LIBs. This anode material was rationally fabricated through the scalable ball-milling method. The nanocomposite structure of P/CNG improves the electron conductivity and alleviates volume change of raw red P because of the three-dimension (3D) framework, massive defects and active sites of CNG sheets. As expected, the P/CNG composite shows excellent electrochemical performances, including high capacity (2522.6 mA h/g at 130 mA/g), remarkable rate capability (1340.5 mA h/g at 3900 mA/g), and great cyclability (1470.1 mA h/g at 1300 mA/g for 300 cycles). This work may provide a broad prospect for a great rate performance of P-based anode material for LIBs.

Authors+Show Affiliations

State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.Lomonosov Moscow State University , Leninskie 1 , Moscow 119991 , Russia.Lomonosov Moscow State University , Leninskie 1 , Moscow 119991 , Russia.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China. Department of Physics , Chalmers University of Technology , Gothenburg SE 412 96 , Sweden.State Key Laboratory for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

31373484

Citation

Jiao, Xingxing, et al. "Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries." ACS Applied Materials & Interfaces, vol. 11, no. 34, 2019, pp. 30858-30864.
Jiao X, Liu Y, Li T, et al. Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries. ACS Appl Mater Interfaces. 2019;11(34):30858-30864.
Jiao, X., Liu, Y., Li, T., Zhang, C., Xu, X., Kapitanova, O. O., He, C., Li, B., Xiong, S., & Song, J. (2019). Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries. ACS Applied Materials & Interfaces, 11(34), 30858-30864. https://doi.org/10.1021/acsami.9b08915
Jiao X, et al. Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries. ACS Appl Mater Interfaces. 2019 Aug 28;11(34):30858-30864. PubMed PMID: 31373484.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries. AU - Jiao,Xingxing, AU - Liu,Yangyang, AU - Li,Tongtong, AU - Zhang,Chaofan, AU - Xu,Xieyu, AU - Kapitanova,Olesya O, AU - He,Cheng, AU - Li,Bing, AU - Xiong,Shizhao, AU - Song,Jiangxuan, Y1 - 2019/08/15/ PY - 2019/8/3/pubmed PY - 2019/8/3/medline PY - 2019/8/3/entrez KW - P−O−C bond KW - anode KW - lithium-ion batteries KW - nitrogen-doped graphene KW - phosphorus SP - 30858 EP - 30864 JF - ACS applied materials & interfaces JO - ACS Appl Mater Interfaces VL - 11 IS - 34 N2 - Red phosphorus (P) has recently gained wide attention because of the high theoretical capacity of 2596 mA h/g, which has been regarded as promising anode material for lithium-ion batteries (LIBs). However, the actual application of red P in LIBs is hampered by the huge expansion of volume and low electronic conductivity. Herein, we design a kind of red phosphorus/crumpled nitrogen-doped graphene (P/CNG) nanocomposites with high capacity density and great rate performance as anode material for LIBs. This anode material was rationally fabricated through the scalable ball-milling method. The nanocomposite structure of P/CNG improves the electron conductivity and alleviates volume change of raw red P because of the three-dimension (3D) framework, massive defects and active sites of CNG sheets. As expected, the P/CNG composite shows excellent electrochemical performances, including high capacity (2522.6 mA h/g at 130 mA/g), remarkable rate capability (1340.5 mA h/g at 3900 mA/g), and great cyclability (1470.1 mA h/g at 1300 mA/g for 300 cycles). This work may provide a broad prospect for a great rate performance of P-based anode material for LIBs. SN - 1944-8252 UR - https://www.unboundmedicine.com/medline/citation/31373484/Crumpled_Nitrogen_Doped_Graphene_Wrapped_Phosphorus_Composite_as_a_Promising_Anode_for_Lithium_Ion_Batteries_ L2 - https://dx.doi.org/10.1021/acsami.9b08915 DB - PRIME DP - Unbound Medicine ER -
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