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Ultrasonic preparation of near-infrared emission cluster-based YbIII and NdIII coordination materials: Ratiometric temperature sensing, selective antibiotics detection and "turn-on" discrimination of l-arginine.
Ultrason Sonochem 2019; 59:104734US

Abstract

Currently near-infrared (NIR) luminescence of lanthanide ions has received great attention because of their unique emissions in the near-infrared region (800-1700 nm). These NIR luminescent materials behave excellent applications in many fields such as sensors and probes in optical amplification, laser systems, biological systems and organic light-emitting diodes. In this work, two new near-infrared (NIR) emission three-dimensional (3D) YbIII and NdIII cluster-based coordination materials, namely {[Yb2(L)2(DMF)(H2O)4]·(DMF)2 (H2O)}n (NIR-MOF 1) and [Nd(L)(DMF)2]n (NIR-MOF 2) (H3L = terphenyl-3,4″,5-tricarboxylic acid) have been synthesized through the facile sono-chemical preparation methods. Both the near-infrared materials 1 and 2 have been characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). Further the mixed-lanthanide near-infrared emission material Nd0.35Yb0.65L (NIR-MOF 3) can also be prepared under the sono-chemical conditions. NIR-MOF 3 can be successfully applied as the ratiometric NIR-MOF-based thermometer, which should origin from the emission intensity ratio between Yb3+ (976 nm) and Nd3+ (1056 nm) in the temperature range of 308-348 K. Besides these, the micro-morphologies of NIR-MOF 1 can be deliberately tuned through different sono-chemical reaction factors (reaction time, reaction temperature and sono-chemical powers). These tuned nano-sized materials NIR-MOF 1 (100 W, 80 min) can be utilized as the fluorescent sensing material to distinguish furazolidone and sulfasalazine from other antibiotics. At the same time, NIR-MOF 2 can be applied as the first example of MOFs-based sensors for discriminating l-arginine from other amino acids through the "turn-on" mode in the near-infrared emission region.

Authors+Show Affiliations

Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China.Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China.Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China.Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China.Tianjin Normal University, Tianjin 300387, PR China.Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China.Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China. Electronic address: hxxyliuk@tjnu.edu.cn.Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry (Tianjin Normal University), Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, PR China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, PR China. Electronic address: hxxydb@tjnu.edu.cn.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

31479886

Citation

Wang, Xing Ze, et al. "Ultrasonic Preparation of Near-infrared Emission Cluster-based YbIII and NdIII Coordination Materials: Ratiometric Temperature Sensing, Selective Antibiotics Detection and "turn-on" Discrimination of L-arginine." Ultrasonics Sonochemistry, vol. 59, 2019, p. 104734.
Wang XZ, Wang XR, Liu YY, et al. Ultrasonic preparation of near-infrared emission cluster-based YbIII and NdIII coordination materials: Ratiometric temperature sensing, selective antibiotics detection and "turn-on" discrimination of l-arginine. Ultrason Sonochem. 2019;59:104734.
Wang, X. Z., Wang, X. R., Liu, Y. Y., Huo, J. Z., Li, Y., Wang, Q., ... Ding, B. (2019). Ultrasonic preparation of near-infrared emission cluster-based YbIII and NdIII coordination materials: Ratiometric temperature sensing, selective antibiotics detection and "turn-on" discrimination of l-arginine. Ultrasonics Sonochemistry, 59, p. 104734. doi:10.1016/j.ultsonch.2019.104734.
Wang XZ, et al. Ultrasonic Preparation of Near-infrared Emission Cluster-based YbIII and NdIII Coordination Materials: Ratiometric Temperature Sensing, Selective Antibiotics Detection and "turn-on" Discrimination of L-arginine. Ultrason Sonochem. 2019;59:104734. PubMed PMID: 31479886.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ultrasonic preparation of near-infrared emission cluster-based YbIII and NdIII coordination materials: Ratiometric temperature sensing, selective antibiotics detection and "turn-on" discrimination of l-arginine. AU - Wang,Xing Ze, AU - Wang,Xin Rui, AU - Liu,Yuan Yuan, AU - Huo,Jian Zhong, AU - Li,Yong, AU - Wang,Qian, AU - Liu,Kun, AU - Ding,Bin, Y1 - 2019/08/16/ PY - 2019/04/29/received PY - 2019/07/19/revised PY - 2019/08/14/accepted PY - 2019/9/4/pubmed PY - 2019/9/4/medline PY - 2019/9/4/entrez KW - Fluorescent sensor KW - Furazolidone KW - Near-infrared KW - Sulfasalazine KW - Temperature sensing KW - l-Arginine SP - 104734 EP - 104734 JF - Ultrasonics sonochemistry JO - Ultrason Sonochem VL - 59 N2 - Currently near-infrared (NIR) luminescence of lanthanide ions has received great attention because of their unique emissions in the near-infrared region (800-1700 nm). These NIR luminescent materials behave excellent applications in many fields such as sensors and probes in optical amplification, laser systems, biological systems and organic light-emitting diodes. In this work, two new near-infrared (NIR) emission three-dimensional (3D) YbIII and NdIII cluster-based coordination materials, namely {[Yb2(L)2(DMF)(H2O)4]·(DMF)2 (H2O)}n (NIR-MOF 1) and [Nd(L)(DMF)2]n (NIR-MOF 2) (H3L = terphenyl-3,4″,5-tricarboxylic acid) have been synthesized through the facile sono-chemical preparation methods. Both the near-infrared materials 1 and 2 have been characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). Further the mixed-lanthanide near-infrared emission material Nd0.35Yb0.65L (NIR-MOF 3) can also be prepared under the sono-chemical conditions. NIR-MOF 3 can be successfully applied as the ratiometric NIR-MOF-based thermometer, which should origin from the emission intensity ratio between Yb3+ (976 nm) and Nd3+ (1056 nm) in the temperature range of 308-348 K. Besides these, the micro-morphologies of NIR-MOF 1 can be deliberately tuned through different sono-chemical reaction factors (reaction time, reaction temperature and sono-chemical powers). These tuned nano-sized materials NIR-MOF 1 (100 W, 80 min) can be utilized as the fluorescent sensing material to distinguish furazolidone and sulfasalazine from other antibiotics. At the same time, NIR-MOF 2 can be applied as the first example of MOFs-based sensors for discriminating l-arginine from other amino acids through the "turn-on" mode in the near-infrared emission region. SN - 1873-2828 UR - https://www.unboundmedicine.com/medline/citation/31479886/Ultrasonic_preparation_of_near-infrared_emission_cluster-based_YbIII_and_NdIII_coordination_materials:_Ratiometric_temperature_sensing,_selective_antibiotics_detection_and_"turn-on"_discrimination_of_l-arginine L2 - https://linkinghub.elsevier.com/retrieve/pii/S1350-4177(19)30657-1 DB - PRIME DP - Unbound Medicine ER -