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Synthesis and characterization of κ-carrageenan bio-nanocomposite films reinforced with bentonite nanoclay.
Int J Biol Macromol. 2020 Jul 01; 154:9-17.IJ

Abstract

Due to ecological reason, in the last period there is an increased interest for changing the synthetic based materials with biodegradable ones. In this study, we prepared bio-nanocomposite formulations based on κ-Carrageenan (κ) and bentonite nanoclay (BT) with different component concentrations (0% BT, 5% BT, 10% BT and 15% BT respectively) and investigated their structural features, with focus on the interactions, sorption properties, and how the combination between them influences these properties. By infrared spectroscopy was identified that in the blending process hydrogen bonds and/or electrostatic interactions may have occurred between BT and κ. The water uptake and water sorption ability decreased with the increasing of the BT content in the formulations, from about 12% for κ to 9% for κ-BT 85:15% and from about 128% for κ to 121% for κ-BT 85:15%, respectively. Water adsorption can significantly decrease if the reinforcement materials are homogenusly dispersed in the matrix. The increase of the BT content induced also a decrease of the water contact angle at the surface from 76o for κ to 27o for κ-BT 85:15%.

Authors+Show Affiliations

Petru Poni Institute of Macromolecular Chemistry of the Romanian Academy, Iasi, Romania.Petru Poni Institute of Macromolecular Chemistry of the Romanian Academy, Iasi, Romania.Petru Poni Institute of Macromolecular Chemistry of the Romanian Academy, Iasi, Romania. Electronic address: cpopescu@icmpp.ro.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

32173433

Citation

Dogaru, Bianca-Ioana, et al. "Synthesis and Characterization of Κ-carrageenan Bio-nanocomposite Films Reinforced With Bentonite Nanoclay." International Journal of Biological Macromolecules, vol. 154, 2020, pp. 9-17.
Dogaru BI, Simionescu B, Popescu MC. Synthesis and characterization of κ-carrageenan bio-nanocomposite films reinforced with bentonite nanoclay. Int J Biol Macromol. 2020;154:9-17.
Dogaru, B. I., Simionescu, B., & Popescu, M. C. (2020). Synthesis and characterization of κ-carrageenan bio-nanocomposite films reinforced with bentonite nanoclay. International Journal of Biological Macromolecules, 154, 9-17. https://doi.org/10.1016/j.ijbiomac.2020.03.088
Dogaru BI, Simionescu B, Popescu MC. Synthesis and Characterization of Κ-carrageenan Bio-nanocomposite Films Reinforced With Bentonite Nanoclay. Int J Biol Macromol. 2020 Jul 1;154:9-17. PubMed PMID: 32173433.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Synthesis and characterization of κ-carrageenan bio-nanocomposite films reinforced with bentonite nanoclay. AU - Dogaru,Bianca-Ioana, AU - Simionescu,Bogdan, AU - Popescu,Maria-Cristina, Y1 - 2020/03/12/ PY - 2019/12/01/received PY - 2020/03/04/revised PY - 2020/03/11/accepted PY - 2020/3/17/pubmed PY - 2021/2/16/medline PY - 2020/3/17/entrez KW - Bentonite nanoclay KW - Interactions KW - Nanocomposite films KW - Sorption properties KW - κ-Carrageenan SP - 9 EP - 17 JF - International journal of biological macromolecules JO - Int J Biol Macromol VL - 154 N2 - Due to ecological reason, in the last period there is an increased interest for changing the synthetic based materials with biodegradable ones. In this study, we prepared bio-nanocomposite formulations based on κ-Carrageenan (κ) and bentonite nanoclay (BT) with different component concentrations (0% BT, 5% BT, 10% BT and 15% BT respectively) and investigated their structural features, with focus on the interactions, sorption properties, and how the combination between them influences these properties. By infrared spectroscopy was identified that in the blending process hydrogen bonds and/or electrostatic interactions may have occurred between BT and κ. The water uptake and water sorption ability decreased with the increasing of the BT content in the formulations, from about 12% for κ to 9% for κ-BT 85:15% and from about 128% for κ to 121% for κ-BT 85:15%, respectively. Water adsorption can significantly decrease if the reinforcement materials are homogenusly dispersed in the matrix. The increase of the BT content induced also a decrease of the water contact angle at the surface from 76o for κ to 27o for κ-BT 85:15%. SN - 1879-0003 UR - https://www.unboundmedicine.com/medline/citation/32173433/Synthesis_and_characterization_of_κ_carrageenan_bio_nanocomposite_films_reinforced_with_bentonite_nanoclay_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0141-8130(19)39868-X DB - PRIME DP - Unbound Medicine ER -