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Analysis of Extra Virgin Olive Oils from Two Italian Regions by Means of Proton Nuclear Magnetic Resonance Relaxation and Relaxometry Measurements.
J Agric Food Chem. 2021 Oct 20; 69(41):12073-12080.JA

Abstract

The interest in development of new non-destructive methods for characterization of extra virgin olive oils (EVOOs) has been increasing in the recent years. Among different experimental techniques, nuclear magnetic resonance (NMR) relaxation measurements are very promising in the field of food characterization and authentication. In this study, we focused on relaxation times T1 and T2 measured at different magnetic field strengths (namely, 2, 100, and 400 MHz) and 1H NMR T1 relaxometry dispersions directly on olive oil samples without any chemical/physical treatments. A large set of EVOO samples produced in two regions of Italy, Tuscany and Apulia, were investigated by means of 1H NMR relaxation techniques. The relaxation studies reported here show several common features between the two sets of EVOO samples, thus indicating that relaxation properties, namely, the ranges of values of T1 and T2 at 2 and 100 MHz, are characteristic of EVOOs, independently from the cultivars, climate, and geographic origin. This is a promising result in view of quality control and monitoring.

Authors+Show Affiliations

Department of Condensed Matter Physics, Jožef Stefan Institute, 39 Jamova Cesta, SI-1000 Ljubljana, Slovenia.Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 3, 56124 Pisa, Italy.Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 3, 56124 Pisa, Italy.Department of Condensed Matter Physics, Jožef Stefan Institute, 39 Jamova Cesta, SI-1000 Ljubljana, Slovenia.Department of Condensed Matter Physics, Jožef Stefan Institute, 39 Jamova Cesta, SI-1000 Ljubljana, Slovenia.Department of Condensed Matter Physics, Jožef Stefan Institute, 39 Jamova Cesta, SI-1000 Ljubljana, Slovenia.Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 3, 56124 Pisa, Italy.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

33847493

Citation

Gradišek, Anton, et al. "Analysis of Extra Virgin Olive Oils From Two Italian Regions By Means of Proton Nuclear Magnetic Resonance Relaxation and Relaxometry Measurements." Journal of Agricultural and Food Chemistry, vol. 69, no. 41, 2021, pp. 12073-12080.
Gradišek A, Cifelli M, Ancora D, et al. Analysis of Extra Virgin Olive Oils from Two Italian Regions by Means of Proton Nuclear Magnetic Resonance Relaxation and Relaxometry Measurements. J Agric Food Chem. 2021;69(41):12073-12080.
Gradišek, A., Cifelli, M., Ancora, D., Sepe, A., Zalar, B., Apih, T., & Domenici, V. (2021). Analysis of Extra Virgin Olive Oils from Two Italian Regions by Means of Proton Nuclear Magnetic Resonance Relaxation and Relaxometry Measurements. Journal of Agricultural and Food Chemistry, 69(41), 12073-12080. https://doi.org/10.1021/acs.jafc.1c00622
Gradišek A, et al. Analysis of Extra Virgin Olive Oils From Two Italian Regions By Means of Proton Nuclear Magnetic Resonance Relaxation and Relaxometry Measurements. J Agric Food Chem. 2021 Oct 20;69(41):12073-12080. PubMed PMID: 33847493.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Analysis of Extra Virgin Olive Oils from Two Italian Regions by Means of Proton Nuclear Magnetic Resonance Relaxation and Relaxometry Measurements. AU - Gradišek,Anton, AU - Cifelli,Mario, AU - Ancora,Donatella, AU - Sepe,Ana, AU - Zalar,Boštjan, AU - Apih,Tomaž, AU - Domenici,Valentina, Y1 - 2021/04/13/ PY - 2021/4/14/pubmed PY - 2021/10/24/medline PY - 2021/4/13/entrez KW - 1H NMR relaxometry KW - EVOO KW - T1 KW - T2 KW - lipids KW - molecular dynamics KW - olive oil SP - 12073 EP - 12080 JF - Journal of agricultural and food chemistry JO - J Agric Food Chem VL - 69 IS - 41 N2 - The interest in development of new non-destructive methods for characterization of extra virgin olive oils (EVOOs) has been increasing in the recent years. Among different experimental techniques, nuclear magnetic resonance (NMR) relaxation measurements are very promising in the field of food characterization and authentication. In this study, we focused on relaxation times T1 and T2 measured at different magnetic field strengths (namely, 2, 100, and 400 MHz) and 1H NMR T1 relaxometry dispersions directly on olive oil samples without any chemical/physical treatments. A large set of EVOO samples produced in two regions of Italy, Tuscany and Apulia, were investigated by means of 1H NMR relaxation techniques. The relaxation studies reported here show several common features between the two sets of EVOO samples, thus indicating that relaxation properties, namely, the ranges of values of T1 and T2 at 2 and 100 MHz, are characteristic of EVOOs, independently from the cultivars, climate, and geographic origin. This is a promising result in view of quality control and monitoring. SN - 1520-5118 UR - https://www.unboundmedicine.com/medline/citation/33847493/Analysis_of_Extra_Virgin_Olive_Oils_from_Two_Italian_Regions_by_Means_of_Proton_Nuclear_Magnetic_Resonance_Relaxation_and_Relaxometry_Measurements_ DB - PRIME DP - Unbound Medicine ER -