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Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry.
Foods. 2021 Oct 21; 10(11)F

Abstract

The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC2-QTOF MS). A total of 52, 53, 52, 59 and 58 TAGs were detected and tentatively identified from the blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils, respectively, according to their accurate molecular weight in MS1 and fragment ion profiles in MS2. OLL was the most abundant TAG in the blackberry, red raspberry and black raspberry seed oils. Furthermore, the fatty acid compositions of the five berry seed oils were directly determined by gas chromatography coupled with mass spectrometry (GC-MS). In addition, the seed oils had total phenolic contents ranging 13.68-177.06 µmol GAE (gallic acid equivalent)/L oil, and significant scavenging capacities against DPPH, peroxyl, and ABTS+ radicals. These results indicated that the combination of UPC2 and QTOF MS could effectively identify and semi-quantify the TAGs compositions of the berry seed oils with sn-position information for the fatty acids. Understanding the TAGs compositions of these berry seed oils could improve the utilization of these potentially high nutritional value oils for human health.

Authors+Show Affiliations

College of Food Science and Nutritional Engineering, National Engineering Research Center for Fruit and Vegetable Processing, Key Laboratory of Fruit and Vegetable Processing Ministry of Agriculture, Engineering Research Centre for Fruit and Vegetable Processing, Ministry of Education, China Agricultural University, Beijing 100083, China.Institute of Food and Nutraceutical Science, School of Agriculture & Biology, Shanghai Jiao Tong University, Shanghai 200240, China.Institute of Food and Nutraceutical Science, School of Agriculture & Biology, Shanghai Jiao Tong University, Shanghai 200240, China.Bluewood Associaes Co., Ltd., Suzhou 215134, China.Institute of Food and Nutraceutical Science, School of Agriculture & Biology, Shanghai Jiao Tong University, Shanghai 200240, China. Department of Nutrition and Food Science, University of Maryland, College Park, MD 20742, USA.Department of Nutrition and Food Science, University of Maryland, College Park, MD 20742, USA.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

34828811

Citation

Luo, Yinghua, et al. "Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils By Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry." Foods (Basel, Switzerland), vol. 10, no. 11, 2021.
Luo Y, Yuan F, Li Y, et al. Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry. Foods. 2021;10(11).
Luo, Y., Yuan, F., Li, Y., Wang, J. D., Gao, B., & Yu, L. L. (2021). Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry. Foods (Basel, Switzerland), 10(11). https://doi.org/10.3390/foods10112530
Luo Y, et al. Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils By Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry. Foods. 2021 Oct 21;10(11) PubMed PMID: 34828811.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry. AU - Luo,Yinghua, AU - Yuan,Fanghao, AU - Li,Yanfang, AU - Wang,Junyi Danny, AU - Gao,Boyan, AU - Yu,Liangli Lucy, Y1 - 2021/10/21/ PY - 2021/09/19/received PY - 2021/10/18/revised PY - 2021/10/19/accepted PY - 2021/11/27/entrez PY - 2021/11/28/pubmed PY - 2021/11/28/medline KW - berry seed oils KW - quadrupole time-of-flight mass spectrometry (QTOF MS) KW - triacylglycerol (TAG) compositions KW - ultra-performance convergence chromatography (UPC2) JF - Foods (Basel, Switzerland) JO - Foods VL - 10 IS - 11 N2 - The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC2-QTOF MS). A total of 52, 53, 52, 59 and 58 TAGs were detected and tentatively identified from the blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils, respectively, according to their accurate molecular weight in MS1 and fragment ion profiles in MS2. OLL was the most abundant TAG in the blackberry, red raspberry and black raspberry seed oils. Furthermore, the fatty acid compositions of the five berry seed oils were directly determined by gas chromatography coupled with mass spectrometry (GC-MS). In addition, the seed oils had total phenolic contents ranging 13.68-177.06 µmol GAE (gallic acid equivalent)/L oil, and significant scavenging capacities against DPPH, peroxyl, and ABTS+ radicals. These results indicated that the combination of UPC2 and QTOF MS could effectively identify and semi-quantify the TAGs compositions of the berry seed oils with sn-position information for the fatty acids. Understanding the TAGs compositions of these berry seed oils could improve the utilization of these potentially high nutritional value oils for human health. SN - 2304-8158 UR - https://www.unboundmedicine.com/medline/citation/34828811/Triacylglycerol_and_Fatty_Acid_Compositions_of_Blackberry_Red_Raspberry_Black_Raspberry_Blueberry_and_Cranberry_Seed_Oils_by_Ultra_Performance_Convergence_Chromatography_Quadrupole_Time_of_Flight_Mass_Spectrometry_ L2 - https://www.mdpi.com/resolver?pii=foods10112530 DB - PRIME DP - Unbound Medicine ER -
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