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Intelligent pH-sensing film based on polyvinyl alcohol/cellulose nanocrystal with purple cabbage anthocyanins for visually monitoring shrimp freshness.
Int J Biol Macromol. 2022 Oct 01; 218:900-908.IJ

Abstract

We aimed to prepare a new pH-sensing film based on the immobilization of purple cabbage anthocyanins (PCA) into Polyvinyl alcohol (PVA) reinforced by cellulose nanocrystals (CNC). FT-IR, XRD and TGA were used to assess the intermolecular interactions and thermo-stability of films. The addition of CNC and PCA resulted in an enhancement in UV-vis barrier, mechanical properties and moisture resistance. Inclusion of PCA imparted intelligent properties to the films. PCA-loaded films displayed strong visually detectable colorimetric responses to pH (2-13) and volatile ammonia. When applied to monitor shrimp freshness at 4 °C, PVA/CNC films containing 0.6 % PCA exhibited conspicuous color fluctuations from purple to gray blue upon deterioration. As a result, PVA/CNC-PCA colorimetric films were considered as intelligent packaging labels with significant mechanical, water vapor barrier properties and pH-sensing qualities for visual quality evaluation of fresh seafood products.

Authors+Show Affiliations

Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China; College of Tropical Crops, Yunnan Agricultural University, Pu'er, Yunnan 665099, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China. Electronic address: weizhou111@foxmail.com.College of Food Science and Technology, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China; Key Laboratory of Precision Nutrition and Food Quality, Ministry of Education, Department of Nutrition and Health, China Agricultural University, Beijing 100083, China. Electronic address: wangzhuo4132@outlook.com.Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China.

Pub Type(s)

Journal Article

Language

eng

PubMed ID

35907457

Citation

He, Yunxia, et al. "Intelligent pH-sensing Film Based On Polyvinyl Alcohol/cellulose Nanocrystal With Purple Cabbage Anthocyanins for Visually Monitoring Shrimp Freshness." International Journal of Biological Macromolecules, vol. 218, 2022, pp. 900-908.
He Y, Lu L, Lin Y, et al. Intelligent pH-sensing film based on polyvinyl alcohol/cellulose nanocrystal with purple cabbage anthocyanins for visually monitoring shrimp freshness. Int J Biol Macromol. 2022;218:900-908.
He, Y., Lu, L., Lin, Y., Li, R., Yuan, Y., Lu, X., Zou, Y., Zhou, W., Wang, Z., & Li, J. (2022). Intelligent pH-sensing film based on polyvinyl alcohol/cellulose nanocrystal with purple cabbage anthocyanins for visually monitoring shrimp freshness. International Journal of Biological Macromolecules, 218, 900-908. https://doi.org/10.1016/j.ijbiomac.2022.07.194
He Y, et al. Intelligent pH-sensing Film Based On Polyvinyl Alcohol/cellulose Nanocrystal With Purple Cabbage Anthocyanins for Visually Monitoring Shrimp Freshness. Int J Biol Macromol. 2022 Oct 1;218:900-908. PubMed PMID: 35907457.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Intelligent pH-sensing film based on polyvinyl alcohol/cellulose nanocrystal with purple cabbage anthocyanins for visually monitoring shrimp freshness. AU - He,Yunxia, AU - Lu,Lun, AU - Lin,Yanyun, AU - Li,Ruyi, AU - Yuan,Yuan, AU - Lu,Xuli, AU - Zou,Ying, AU - Zhou,Wei, AU - Wang,Zhuo, AU - Li,Jihua, Y1 - 2022/07/27/ PY - 2022/05/23/received PY - 2022/07/19/revised PY - 2022/07/24/accepted PY - 2022/7/31/pubmed PY - 2022/9/14/medline PY - 2022/7/30/entrez KW - Cellulose nanocrystals KW - Intelligent pH-sensing film KW - Shrimp freshness SP - 900 EP - 908 JF - International journal of biological macromolecules JO - Int J Biol Macromol VL - 218 N2 - We aimed to prepare a new pH-sensing film based on the immobilization of purple cabbage anthocyanins (PCA) into Polyvinyl alcohol (PVA) reinforced by cellulose nanocrystals (CNC). FT-IR, XRD and TGA were used to assess the intermolecular interactions and thermo-stability of films. The addition of CNC and PCA resulted in an enhancement in UV-vis barrier, mechanical properties and moisture resistance. Inclusion of PCA imparted intelligent properties to the films. PCA-loaded films displayed strong visually detectable colorimetric responses to pH (2-13) and volatile ammonia. When applied to monitor shrimp freshness at 4 °C, PVA/CNC films containing 0.6 % PCA exhibited conspicuous color fluctuations from purple to gray blue upon deterioration. As a result, PVA/CNC-PCA colorimetric films were considered as intelligent packaging labels with significant mechanical, water vapor barrier properties and pH-sensing qualities for visual quality evaluation of fresh seafood products. SN - 1879-0003 UR - https://www.unboundmedicine.com/medline/citation/35907457/Intelligent_pH_sensing_film_based_on_polyvinyl_alcohol/cellulose_nanocrystal_with_purple_cabbage_anthocyanins_for_visually_monitoring_shrimp_freshness_ DB - PRIME DP - Unbound Medicine ER -