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Triterpenoid saponins from Bellis sylvestris. 2. Structures of partially deacylated saponins.
J Nat Prod. 1996 Apr; 59(4):355-9.JN

Abstract

Four saponins have been isolated from the herbal parts of Bellis sylvestris and the same, together with three further compounds, from the underground parts. The structures were elucidated by electrospray ionization mass spectrometry, including tandem mass spectrometry, and by 1D and 2D homonuclear and heteronuclear NMR spectroscopy. Two of the compounds are new saponins with the structures 3-O-beta-D-glucopyranosyl-2 beta, 3 beta, 23-trihydroxyolean-12-en-28-oic acid 28-O-beta-D-glucopyranosyl (1-->3)-[alpha-L-rhamnopyranosyl (1-->2)]-beta-D- glucopyranoside and 3-O-beta-D-glucopyranosyl-2 beta, 3 beta,16 alpha, 23-tetrahydroxyolean-12-en- 28-oic acid 28-O-alpha-L-rhamnopyranosyl (1-->3)-beta-D-xylopyranosyl(1-->4)-alpha-L- rhamnopyranosyl(1-->2)-[(E)-2-butenoic acid (1-->3)]-beta-D-fucopyranoside. Taxonomically these data provide significant evidence of a link between the Bellis genus and Bellium bellidioides.

Authors+Show Affiliations

Schöpke T
Humboldt-Universität zu Berlin, Institut für Pharmazie, Germany. thomas=schoepke@rz.hu-berlin.de
Hiller K
No affiliation info available
Wray V
No affiliation info available
Nimtz M
No affiliation info available
Yamasaki K
No affiliation info available
Kasai R
No affiliation info available

MeSH

Carbohydrate SequenceDealkylationMolecular ConformationMolecular Sequence DataPlants, MedicinalSaponinsTriterpenes

Pub Type(s)

Journal Article

Language

eng

PubMed ID

8699180

Citation

Schöpke, T, et al. "Triterpenoid Saponins From Bellis Sylvestris. 2. Structures of Partially Deacylated Saponins." Journal of Natural Products, vol. 59, no. 4, 1996, pp. 355-9.
Schöpke T, Hiller K, Wray V, et al. Triterpenoid saponins from Bellis sylvestris. 2. Structures of partially deacylated saponins. J Nat Prod. 1996;59(4):355-9.
Schöpke, T., Hiller, K., Wray, V., Nimtz, M., Yamasaki, K., & Kasai, R. (1996). Triterpenoid saponins from Bellis sylvestris. 2. Structures of partially deacylated saponins. Journal of Natural Products, 59(4), 355-9.
Schöpke T, et al. Triterpenoid Saponins From Bellis Sylvestris. 2. Structures of Partially Deacylated Saponins. J Nat Prod. 1996;59(4):355-9. PubMed PMID: 8699180.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Triterpenoid saponins from Bellis sylvestris. 2. Structures of partially deacylated saponins. AU - Schöpke,T, AU - Hiller,K, AU - Wray,V, AU - Nimtz,M, AU - Yamasaki,K, AU - Kasai,R, PY - 1996/4/1/pubmed PY - 1996/4/1/medline PY - 1996/4/1/entrez SP - 355 EP - 9 JF - Journal of natural products JO - J Nat Prod VL - 59 IS - 4 N2 - Four saponins have been isolated from the herbal parts of Bellis sylvestris and the same, together with three further compounds, from the underground parts. The structures were elucidated by electrospray ionization mass spectrometry, including tandem mass spectrometry, and by 1D and 2D homonuclear and heteronuclear NMR spectroscopy. Two of the compounds are new saponins with the structures 3-O-beta-D-glucopyranosyl-2 beta, 3 beta, 23-trihydroxyolean-12-en-28-oic acid 28-O-beta-D-glucopyranosyl (1-->3)-[alpha-L-rhamnopyranosyl (1-->2)]-beta-D- glucopyranoside and 3-O-beta-D-glucopyranosyl-2 beta, 3 beta,16 alpha, 23-tetrahydroxyolean-12-en- 28-oic acid 28-O-alpha-L-rhamnopyranosyl (1-->3)-beta-D-xylopyranosyl(1-->4)-alpha-L- rhamnopyranosyl(1-->2)-[(E)-2-butenoic acid (1-->3)]-beta-D-fucopyranoside. Taxonomically these data provide significant evidence of a link between the Bellis genus and Bellium bellidioides. SN - 0163-3864 UR - https://www.unboundmedicine.com/medline/citation/8699180/Triterpenoid_saponins_from_Bellis_sylvestris__2__Structures_of_partially_deacylated_saponins_ L2 - https://doi.org/10.1021/np9600715 DB - PRIME DP - Unbound Medicine ER -