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Four novel cycloartane glycosides from Astragalus oleifolius.
J Nat Prod. 1996 Nov; 59(11):1019-23.JN

Abstract

Four novel cycloartane-type triterpene glycosides, macrophyllosaponins A-D (1-4) were isolated from the roots of Astragalus oleifolius. By means of chemical (acetylation, alkaline hydrolysis) and spectroscopic methods (IR, 1D- and 2D-NMR, FABMS), their structures were established as 3-O-alpha-L-rhamnopyranosyl-24-O-(4"-O-acetyl)-beta-D-xylopyranosyl-1 alpha,3 beta,7 beta,24(S), 25-pentahydroxycycloartane (1), 3-O-alpha-L-rhamnopyranosyl-24-O-beta-D-xylopyranosyl-1 alpha,3 beta, 7 beta,24(S), 25-pentahydroxycycloartane (2), 3-O-alpha-L-rhamnopyranosyl-25-O-beta-D-glucoyranosyl-1 alpha, 3 beta,7 beta,24(S),25-pentahydroxycycloartane (3), and 3-O-alpha-L-rhamnopyranosyl-24-O-(2-O-beta-D-xylopyranosyl) -beta-D-xylopyranosyl-1 alpha,3 beta,7 beta,24(S), 25-pentahydroxycycloartane (4).

Authors+Show Affiliations

Caliş I
Department of Pharmacognosy, Faculty of Pharmacy, Hacettepe University, Ankara, Turkey.
Zor M
No affiliation info available
Saracoğlu I
No affiliation info available
Işimer A
No affiliation info available
Rüegger H
No affiliation info available

MeSH

Carbohydrate SequenceChromatography, LiquidFabaceaeHydrolysisMagnetic Resonance SpectroscopyMolecular Sequence DataPlant RootsPlants, MedicinalSaponinsSpectrophotometry, InfraredTurkey

Pub Type(s)

Journal Article

Language

eng

PubMed ID

8946742

Citation

Caliş, I, et al. "Four Novel Cycloartane Glycosides From Astragalus Oleifolius." Journal of Natural Products, vol. 59, no. 11, 1996, pp. 1019-23.
Caliş I, Zor M, Saracoğlu I, et al. Four novel cycloartane glycosides from Astragalus oleifolius. J Nat Prod. 1996;59(11):1019-23.
Caliş, I., Zor, M., Saracoğlu, I., Işimer, A., & Rüegger, H. (1996). Four novel cycloartane glycosides from Astragalus oleifolius. Journal of Natural Products, 59(11), 1019-23.
Caliş I, et al. Four Novel Cycloartane Glycosides From Astragalus Oleifolius. J Nat Prod. 1996;59(11):1019-23. PubMed PMID: 8946742.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Four novel cycloartane glycosides from Astragalus oleifolius. AU - Caliş,I, AU - Zor,M, AU - Saracoğlu,I, AU - Işimer,A, AU - Rüegger,H, PY - 1996/11/1/pubmed PY - 1996/11/1/medline PY - 1996/11/1/entrez SP - 1019 EP - 23 JF - Journal of natural products JO - J Nat Prod VL - 59 IS - 11 N2 - Four novel cycloartane-type triterpene glycosides, macrophyllosaponins A-D (1-4) were isolated from the roots of Astragalus oleifolius. By means of chemical (acetylation, alkaline hydrolysis) and spectroscopic methods (IR, 1D- and 2D-NMR, FABMS), their structures were established as 3-O-alpha-L-rhamnopyranosyl-24-O-(4"-O-acetyl)-beta-D-xylopyranosyl-1 alpha,3 beta,7 beta,24(S), 25-pentahydroxycycloartane (1), 3-O-alpha-L-rhamnopyranosyl-24-O-beta-D-xylopyranosyl-1 alpha,3 beta, 7 beta,24(S), 25-pentahydroxycycloartane (2), 3-O-alpha-L-rhamnopyranosyl-25-O-beta-D-glucoyranosyl-1 alpha, 3 beta,7 beta,24(S),25-pentahydroxycycloartane (3), and 3-O-alpha-L-rhamnopyranosyl-24-O-(2-O-beta-D-xylopyranosyl) -beta-D-xylopyranosyl-1 alpha,3 beta,7 beta,24(S), 25-pentahydroxycycloartane (4). SN - 0163-3864 UR - https://www.unboundmedicine.com/medline/citation/8946742/Four_novel_cycloartane_glycosides_from_Astragalus_oleifolius_ L2 - https://doi.org/10.1021/np9604184 DB - PRIME DP - Unbound Medicine ER -