In order to study the suitability of olive mill wastewater (OMW) for composting, this liquid waste was added to two different mixtures of agroindustrial and urban wastes and the composting process was compared with two other piles of similar composition, but without OMW. These four piles were studied in a pilot plant using the Rutgers static pile system. The addition of OMW produced a greater proportion of degradable organic matter or a higher degradation rate, higher electrical conductivity values, greater losses of total N and lower nitrification than in piles without OMW. Its addition also restricted the increase of the cation exchange capacity and provoked the appearance of phytotoxicity or a longer persistence of phytotoxicity. However, in general, all the composts showed increases in the cation exchange capacity, the percentage of humic acid-like carbon, the polymerisation ratio of these humic substances (which revealed that the organic matter had been humified during composting) and the germination index, the latter indicating the reduction of phytotoxicity during the process.