Mild rhodium(III)-catalyzed cyclization of amides with α,β-unsaturated aldehydes and ketones to azepinones: application to the synthesis of the homoprotoberberine framework.
Angew Chem Int Ed Engl. 2013 May 10; 52(20):5393-7.AC

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Authors+Show Affiliations

Shi Z
Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149 Münster, Germany.
Grohmann C
No affiliation info available
Glorius F
No affiliation info available

MeSH

AldehydesAzepinesBenzamidesBerberine AlkaloidsCatalysisCyclizationCycloaddition ReactionHydrogen BondingKetonesMolecular StructureRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23592552