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50,196 results
  • Impact of Rigidity on Molecular Self-Assembly. [Journal Article]
    Langmuir 2019King E, Gebbie M, Melosh NA
  • Rigid, cage-like molecules, like diamondoids, show unique self-assembly behavior, such as templating 1-D nanomaterial assembly via pathways that are typically blocked for such bulky substituents. We investigate molecular forces between diamondoids to explore why molecules with high structural rigidity exhibit these novel assembly pathways. The rigid nature of diamondoids significantly lowers conf…
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