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21 results
  • Aspects of the topology of actinide atom substructures in crystal structures and the concept of antiliquid. [Journal Article]
    Acta Crystallogr A Found Adv 2019; 75(Pt 2):370-378Serezhkin VN, Rogaleva EF, … Serezhkina LB
  • Using the parameters of Voronoi-Dirichlet (VD) polyhedra the authors have verified the maximum space-filling principle in substructures constructed of actinide atoms (from thorium to einsteinium) in all crystal structures from the Inorganic Crystal Structure Database (ICSD) and Cambridge Structural Database (CSD). It is shown that most of the actinide atoms in such substructures are surrounded by…
  • Revisiting complexation thermodynamics of transplutonium elements up to einsteinium. [Journal Article]
    Chem Commun (Camb) 2018; 54(75):10578-10581Kelley MP, Bessen NP, … Shafer JC
  • Literature casts einsteinium as a departure from earlier transplutonium actinides, with a decrease in stability constants with aminopolycarboxylate ligands. This report studies transplutonium chemistry - including Am, Bk, Cf, and Es - with aminopolycarboxylate ligands. Es complexation follows similar thermodynamic and structural trends established by the earlier actinides, consistent with first-p…
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