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54,351 results
  • Annulation of Oxime-Ether Tethered Donor-Acceptor Cyclopropanes. [Journal Article]
    Chemistry 2019Kerr MA, Irwin L, … Vriesen M
  • Oxime-ether tethered cyclopropanes when exposed to Yb(OTf)3 and heat annulated to generate hydropyrrolo-oxazines products that could be taken to their respective pyrrolidines via hydrogenative N-O bond cleavage. The hydropyrrolo-oxazines were generated in a diastereoselective manner isolating the cis or trans product based on the temperature of the reaction. 20 examples of selective cis and trans…
  • Origin of lithium whisker formation and growth under stress. [Journal Article]
    Nat Nanotechnol 2019He Y, Ren X, … Wang C
  • Lithium metal has the lowest standard electrochemical redox potential and very high theoretical specific capacity, making it the ultimate anode material for rechargeable batteries. However, its application in batteries has been impeded by the formation of Li whiskers, which consume the electrolyte, deplete active Li and may lead to short-circuit of the battery. Tackling these issues successfully …
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