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125,436 results
  • Modulation of Prins Cyclization by Vibrational Strong Coupling. [Journal Article]
    Angew Chem Int Ed Engl 2020Hirai K, Takeda R, … Uji-I H
  • Light-molecule strong coupling has emerged within the last decade as an entirely new method to control chemical reactions. A few years ago it was discovered that the chemical reactivity could be altered by vibrational strong coupling (VSC). While the potential of VSC in organic chemistry appears enormous, only a limited number of reactions have been investigated under VSC to date, including solvo…
  • SGLT2 Inhibitors Play a Salutary Role in Heart Failure via Modulation of the Mitochondrial Function. [Review]
    Front Cardiovasc Med 2019; 6:186Maejima Y
  • Three cardiovascular outcome trials of sodium glucose cotransporter 2 (SGLT2) inhibitors, including the EMPA-REG OUTCOME trial, CANVAS Program, and DECLARE TIMI 58 trial, revealed that SGLT2 inhibitors were superior to a matching placebo in reducing cardiovascular events, including mortality and hospitalization for heart failure, in patients with type 2 diabetes. However, the detailed mechanism u…
  • Ferrocene-Biotin Conjugates: Synthesis, Structure, Cytotoxic Activity and Interaction with Avidin. [Journal Article]
    Chempluschem 2016; 81(11):1191-1201Błauż A, Rychlik B, … Plażuk D
  • Friedel-Crafts acylation of ferrocene with d-biotin, d-homobiotin and d-desthiobiotin gave ferrocenyl ketones. These compounds were diastereoselectively reduced to the corresponding alcohols using (R)- and (S)-Me-CBS-oxazaborolidine-borane complexes as reducing agents. The alcohols were further transformed into azido and finally to amino derivatives with retention of configuration, as confirmed b…
  • 1,3-Diaryl-β-diketone Organic Crystals with Red Amplified Spontaneous Emission. [Journal Article]
    Chempluschem 2016; 81(12):1320-1325Tang B, Zhang H, … Zhang H
  • In this study, 1-[4-(dimethylamino)phenyl]-3-(1-hydroxynaphthalen-2-yl)propane-1,3-dione (DPHND) was designed and synthesized to construct red-emissive organic solids. Although DPHND was weakly yellow fluorescent in organic solvents, its emission intensity showed a significant enhancement when a relatively large amount of poor solvent was added, and displayed typical aggregation-induced enhanced …
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