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1,934 results
  • Understanding the effects of solvate ionic liquids as solvents on substitution processes. [Journal Article]
    Org Biomol Chem 2019Schaffarczyk McHale KS, Wong MJ, … Harper JB
  • The effects of solvate ionic liquids as solvents have been considered for two substitution processes where the solvent effects of typical ionic liquids have been extensively investigated previously; the bimolecular nucleophilic substitution (SN2) reaction between pyridine and benzyl bromide and the nucleophilic aromatic substitution (SNAr) reaction between ethanol and 1-fluoro-2,4-dinitrobenzene.…
  • A threefold superstructure of the anti-epileptic drug phenytoin sodium as a mixed methanol solvate hydrate. [Journal Article]
    Acta Crystallogr C Struct Chem 2019; 75(Pt 9):1213-1219Shah HS, Chaturvedi K, … Morris K
  • Phenytoin sodium, a salt of 5,5-diphenylimidazolidine-2,4-dione, or phenytoin, is commercially available in various dosage forms for its anti-epileptic properties to treat and prevent seizures. The title compound, poly[aquatris(μ3-4,4-diphenyl-2,5-dioxoimidazolidin-1-ido)trimethanoltrisodium(I)], [Na3(C15H11N2O2)3(CH4O)3(H2O)1.08]n, a methanol solvate and hydrate of phenytoin sodium, forms a modu…
  • Influence of Hydration on the Structure of Reline Deep Eutectic Solvent: A Molecular Dynamics Study. [Journal Article]
    ACS Omega 2018; 3(11):15246-15255Kumari P, Shobhna , … Kashyap HK
  • In this article, we have performed an all-atom molecular dynamics simulation study to investigate the influence of water on the molecular level arrangement of reline deep eutectic solvent for different hydration levels ranging from 3.4 to 58.1 wt % of water and complemented the observations of recently measured neutron scattering experimental data. This study is particularly important because wat…
  • Palladium(II) complexes of a bridging amine bis-(phenolate) ligand featuring κ2 and κ3 coordination modes. [Journal Article]
    Acta Crystallogr E Crystallogr Commun 2019; 75(Pt 8):1265-1269Graziano BJ, Wile BM, Zeller M
  • Bidentate and tridentate coordination of a 2,4-di-tert-butyl-substituted bridging amine bis-(phenolate) ligand to a palladium(II) center are observed within the same crystal structure, namely di-chlorido-({6,6'-[(ethane-1,2-diylbis(methyl-aza-nedi-yl)]bis-(methyl-ene)}bis-(2,4-di-tert-butyl-phenol))palladium(II) chlorido-(2,4-di-tert-butyl-6-{[(2-{[(3,5-di-tert-butyl-2-hy-droxy-phen-yl)meth-yl](m…
  • Crystal structure and Hirshfeld surface analysis of 2,5-di-bromo-terephthalic acid ethyl-ene glycol monosolvate. [Journal Article]
    Acta Crystallogr E Crystallogr Commun 2019; 75(Pt 8):1228-1231Khotchasanthong K, Jittirattanakun S, … Chainok K
  • The title compound, C8H4Br2O4·C2H6O2, crystallizes with one-half of a 2,5-di-bromo-terephthalic acid (H2Br2tp) mol-ecule and one-half of an ethyl-ene glycol (EG) mol-ecule in the the asymmetric unit. The whole mol-ecules are generated by application of inversion symmetry. The H2Br2tp mol-ecule is not planar, with the di-bromo-benzene ring system inclined by a dihedral angle of 18.62 (3)° to the c…
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