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63 results
  • Macrolactamization Approaches to Arylomycin Antibiotics Core. [Journal Article]
    Org Lett 2019; 21(1):147-151Lim NK, Linghu X, … Gosselin F
  • Two practical entries to arylomycin antibiotics core structures are investigated. In route A, the activation of l-Hpg for the key macrolactamization step is achieved in 89% yield in the presence of unprotected phenol and amine functionalities. Alternatively, a propanephosphonic acid anhydride (T3P)-promoted coupling between thel-Tyr and l-Ala moieties in route B led to a facile macrolactamization…
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